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- Money can't buy auction in aid of children in need live from the Radio 2 Studio (en)
- Russell Watson, Brenda Edwards, Richard Craker and OMD (en)
- The Script, Charlotte Church and Elaine Paige from BBC Maida Vale Studios (en)
- Bernard Cribbins, Gabriella Cilmi and Jon Allen (en)
- Carly Simon, Craig David and Jonathan Pryce (en)
- Chris De Burgh, John Legend and Sandie Shaw (en)
- Elkie Brooks, Mica Paris and Debbie Reynolds (en)
- Esther Rantzen, Richard Hawley and Joe Longthorne (en)
- Gilbert O'Sullivan, Nell Bryden and Jimmy Carr (en)
- Judie Tzuke, Ruthie Henshall and Seth Lakeman (en)
- June Whitfield, Beverley Knight and Paul Carrack (en)
- Katie Melua, Glen Campbell and Justin Lee Collins (en)
- Kiki Dee and Incognito (en)
- Lulu, Mary Chapin Carpenter and Roy Hudd (en)
- Maureen Lipman, Brian Kennedy and The Real Thing (en)
- Richard Wilson, Marti Pellow and Paloma Faith (en)
- Ricky Gervais, Don McLean and Scouting for Girls (en)
- Ringo Starr, Mika and Nell Bryden (en)
- Ronnie Corbett, Sandi Thom and Ben Montague (en)
- Brian May, Kerry Ellis, Fyfe Dangerfield and Robert Lindsay (en)
- Timothy B. Schmit, Albert Lee and Sheila Hancock (en)
- Tony Christie, Gretchen Peters and Kiri Te Kanawa (en)
- Tony Hadley, Jodie Prenger and Rick Astley (en)
- Westlife, Raul Malo and Thea Gilmore live from BBC Maida Vale Studios (en)
- Andrew Lloyd Webber, David Gray and Sharleen Spiteri (en)
- Natalie Imbruglia, Mick Hucknall and Griff Rhys Jones (en)
- The Hoosiers, Huey Lewis, Tift Merritt and Joshua Radin (en)
- Graham Norton, Billy Ocean, Richard Briers and Red Hurley (en)
- Josh Groban, Rumer and Great British Barbershop Boys (en)
- Peter Alliss, Neil Sedaka, Beth Nielsen Chapman and John Barrowman (en)
- Sharon Corr, Ben's Brother, Leon Russell, and James Martin (en)
- Katherine Jenkins, Patrick Stewart and Chelsea Pensioners (en)
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