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- Fluorous chemistry involves the use of perfluorinated compounds or perfluorinated substituents to facilitate recovery of a catalyst or reaction product. Perfluorinated groups impart unique physical properties including high solubility in perfluorinated solvents. This property can be useful in organic synthesis and separation methods such as solid phase extraction. In practice, a perfluorinated alkyl group is incorporated into an otherwise conventional organic reagent as an affinity tag. These reagents can then be separated from organic solvents by extraction with fluorinated solvents such as perfluorohexane. (en)
- フルオラスケミストリー (fluorous chemistry) とは有機化学の分野のひとつで、アルカンやアルキル基が持つ全ての水素がフッ素に置き換わったペルフルオロアルカンやペルフルオロアルキル基を溶媒、触媒、あるいは置換基(タグ)などとして用い、それらフルオラス化合物同士の親和性や他の溶媒に対する疎溶媒性を特徴的な抽出・精製法、合成法へと応用する化学である。 (ja)
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- 4445 (xsd:nonNegativeInteger)
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- Fluorous chemistry involves the use of perfluorinated compounds or perfluorinated substituents to facilitate recovery of a catalyst or reaction product. Perfluorinated groups impart unique physical properties including high solubility in perfluorinated solvents. This property can be useful in organic synthesis and separation methods such as solid phase extraction. In practice, a perfluorinated alkyl group is incorporated into an otherwise conventional organic reagent as an affinity tag. These reagents can then be separated from organic solvents by extraction with fluorinated solvents such as perfluorohexane. (en)
- フルオラスケミストリー (fluorous chemistry) とは有機化学の分野のひとつで、アルカンやアルキル基が持つ全ての水素がフッ素に置き換わったペルフルオロアルカンやペルフルオロアルキル基を溶媒、触媒、あるいは置換基(タグ)などとして用い、それらフルオラス化合物同士の親和性や他の溶媒に対する疎溶媒性を特徴的な抽出・精製法、合成法へと応用する化学である。 (ja)
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- Fluorous chemistry (en)
- フルオラスケミストリー (ja)
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