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Boron chemical complexes

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  • Boron chemical complexes (en)
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  • Fig. 7. Two cases of the Y pair sites: with one Y atom and two Y atoms . In the latter case, some neighboring boron sites are eliminated because they are too close to the Y site. (en)
  • Fig. 26. Sc4.5–xB57–y+zC3.5–z crystal structure viewed along the [010] direction; 2.5 and 2 unit-cell sizes are depicted along the x-axis and z-axis, respectively. Fig. 27. Two-dimensional presentation of supericosahedron connection in Sc4.5–xB57–y+zC3.5–z and YB66. The central icosahedra of the supericosahedron are dark green. Fig. 28. Locations of the I2 icosahedron in the 2-dimensional supericosahedron framework of Sc4.5–xB57–y+zC3.5–z. (en)
  • Fig. 30. Pillar-like structure unit P1 that consists of icosahedra I1 and I3, irregularly shaped B16 polyhedron and other bridge site atoms. Pillar-like structure unit P2 that consists of icosahedra I2, I5 and I6, B10 polyhedron and other bridge site atoms. Fig. 31. The sliced network structure of the cubic phase, and the -oriented boron network layer of the hexagonal phase. (en)
  • Fig. 21. ScB17C0.25 crystal structure viewed along the c-axis. Icosahedra I1 and I2 form a ring centered by a "tube". The "tube" structure that runs along the c-axis. Partial occupancies of B17 and B18 are ignored. Fig. 22. Experimental HRTEM lattice images and electron diffraction patterns taken along the [0001] and [11{{overline|2}}0] directions. Image simulations are added in the bottom-left insets, and a fragment of the crystal structure is also added to . (en)
  • Fig. 4. Thirteen-icosahedron unit 13B12 , and B80 cluster unit. The excessive bonding in panel is because it assumes that all sites are occupied, whereas the total number of boron atoms is only 42. (en)
  • Fig. 8. B12Si3 polyhedron unit. Darker green spheres represent the sites which are occupied either by Si or B atoms. Unusual linkage between the B12-I5 icosahedra connected via two apex atoms of each icosahedron. (en)
  • Fig. 24. Supertetrahedron T, superoctahedron O and octahedral arrangement of the B10 polyhedra in the Sc0.83–xB10.0–yC0.17+ySi0.083–z crystal structure. (en)
  • Fig. 12. Stacking sequences of homologous icosahedron-based rare-earth borides and their HRTEM lattice images; B4C, REB15.5CN , REB22C2N and REB28.5C4 . Red circles are rare-earth atoms. HRTEM lattice images were obtained for YB15.5CN, YB22C2N and YB28.5C4 compounds. (en)
  • Fig. 18. Twinned B22 icosahedra, boron supertetrahedron constructed by 4 icosahedra. (en)
  • Fig. 11. Structure unit of B4C and c-plane network of B12 icosahedra in the B4C structure. Fig. 13. B12 icosahedron network bridged by nitrogen and carbon atoms. (en)
  • Fig. 19. Network of boron icosahedra, B22 unit network and overall crystal structure of ScB19+xSiy; pink and blue spheres indicate Sc and Si atoms, respectively. (en)
  • Fig. 5b. Schematically drawn boron framework of YB66. Light green spheres show the boron supericosahedra and their relative orientations are indicated by arrows. Dark green spheres correspond to the B80 clusters. Fig. 6. Pair of Y sites in YB66. Light green spheres show the boron supericosahedron and dark green spheres correspond to the B80 clusters. (en)
  • Fig. 16. Si8 ethane-like cluster connects layers of boron icosahedra; a layer of boron icosahedra that lies at the same level as the Si8 cluster is not shown. bonding configuration 3≡Si-C≡3. (en)
  • Fig. 9. The boron network that consists of the icosahedra I1, I2 and I3 and is located at z = 0 plane. The icosahedron I4 lies above and below of this network at z = ± 0.25. The boron network that consists of the I5 icosahedron and B12Si3 polyhedron and is located at z = 0.5 plane. The icosahedron I4 lies above and below this network at z = 0.25 and 0.75. Fig. 10. The b-c network formed by icosahedra I4 and I2 as seen along the a-axis. The network is drawn within the range x = 0.09–0.41. (en)
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  • Crystal structure of boron-rich metal borides (en)
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