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- La spectroscopie neutronique à écho de spin (neutron spin echo ou NSE en anglais) est une technique de spectroscopie proposée dès 1972 par Ferenc Mezei. Les instruments dédiés permettent d'étudier des phénomènes relativement lents à l'échelle microscopique, avec des temps caractéristiques allant jusqu'à quelques centaines de nanosecondes. Son utilisation sur la base de spectromètres à trois axes permet également d'améliorer leur résolution en énergie d'au moins deux ordres de grandeur (E de l'ordre du eV). (fr)
- Neutron spin echo spectroscopy is an inelastic neutron scattering technique invented by in the 1970s, and developed in collaboration with John Hayter. In recognition of his work and in other areas, Mezei was awarded the first in 1999. In magnetic resonance, a spin echo is the refocusing of spin magnetisation by a pulse of resonant electromagnetic radiation. The spin echo spectrometer possesses an extremely high energy resolution (roughly one part in 100,000). Additionally, it measures the density-density correlation (or intermediate scattering function) F(Q,t) as a function of momentum transfer Q and time. Other neutron scattering techniques measure the dynamic structure factor S(Q,ω), which can be converted to F(Q,t) by a Fourier transform, which may be difficult in practice. For weak inelastic features S(Q,ω) is better suited, however, for (slow) relaxations the natural representationis given by F(Q,t). Because of its extraordinary high effective energy resolution compared to other neutron scattering techniques, NSE is an ideal method to observe overdamped internal dynamic modes (relaxations) and other diffusive processes in materials such as a polymer blends, alkane chains, or microemulsions. The extraordinary power of NSE spectrometry was further demonstrated recently by the direct observation of coupled internal protein dynamics in the proteins NHERF1 and Taq polymerase and the adherens junction, allowing the direct visualization of protein nanomachinery in motion.Several elementary reviews of the technique exist. (en)
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