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Carborane acids H(CXB11Y5Z6) (X, Y, Z = H, Alk, F, Cl, Br, CF3) are a class of superacids, some of which are estimated to be at least one million times stronger than 100% pure sulfuric acid in terms of their Hammett acidity function values (H0 ≤ –18) and possess computed pKa values well below –20, establishing them as some of the strongest known Brønsted acids. The best-studied example is the highly chlorinated derivative H(CHB11Cl11). The acidity of H(CHB11Cl11) was found to vastly exceed that of triflic acid, CF3SO3H, and bistriflimide, (CF3SO2)2NH, compounds previously regarded as the strongest isolable acids.

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rdfs:label
  • حمض الكربوران (ar)
  • Carborane acid (en)
  • カルボラン酸 (ja)
  • 카보레인산 (ko)
  • Kwas karboranowy (pl)
  • Ácido carborano (pt)
  • Карборановая кислота (ru)
  • Karboransyra (sv)
  • 碳硼烷酸 (zh)
rdfs:comment
  • حمض الكربوران هو حمض فائق له الصيغة (H(CHB11Cl11 وهو من مركبات الكربورانات، والتي هي مركبات تجميعية عنقودية من الكربون والبورون والهيدروجين، بالإضافة إلى الكلور كما في حالة مركب حمض الكربوران. (ar)
  • 카보레인산(Carborane acid)은 화학식 H(CXB11Y5Z6)를 가지는 화합물들의 총칭으로, 대부분 초강산에 속한다. 2004년 캘리포니아 대학의 와 그의 동료에 의해 발견되었다. (ko)
  • カルボラン酸 (カルボランさん、英: carborane acid) はホウ素原子11個と炭素原子1個からなる二十面体型の分子であり、分子式はH(CHB11Cl11)である。カルボランの塩素置換体であり超酸である。2004年、カリフォルニア大学リバーサイド校のクリストファー・リードが発見した。 (ja)
  • Karboransyra, summaformel H(CHB11Cl11), är en supersyra – betydelsefull inom den organiska kemin, bland annat vid utveckling av vitaminpreparat. Karboransyra fräter inte på glas och kan därför lagras i glaskärl, till skillnad från många andra supersyror. (sv)
  • 碳硼烷酸(化學式:H(CHB11Cl11),英語:Carborane acid) 為一種超強酸,是最強的單一分子酸,酸性為硫酸的一百萬倍、氟磺酸的數百倍。 (zh)
  • 2,3,4,5,6,7,8,9,10,11,12-Ундекахлор-1-карба-клозо-додекаборан(12) (журналистское название Карборановая кислота) — одна из самых сильных кислот (суперкислота), полученных в начале XXI века. Химическая формула — H(CHB11Cl11). Карборановая часть молекулы имеет икосаэдрическую структуру. (ru)
  • Carborane acids H(CXB11Y5Z6) (X, Y, Z = H, Alk, F, Cl, Br, CF3) are a class of superacids, some of which are estimated to be at least one million times stronger than 100% pure sulfuric acid in terms of their Hammett acidity function values (H0 ≤ –18) and possess computed pKa values well below –20, establishing them as some of the strongest known Brønsted acids. The best-studied example is the highly chlorinated derivative H(CHB11Cl11). The acidity of H(CHB11Cl11) was found to vastly exceed that of triflic acid, CF3SO3H, and bistriflimide, (CF3SO2)2NH, compounds previously regarded as the strongest isolable acids. (en)
  • Kwas karboranowy H(CHB11Cl11) to związek chemiczny, superkwas, w którym rolę reszty kwasowej spełnia klasterowy karboran. Jest to aktualnie kwas o największej mocy, który można wyodrębnić z roztworu w stanie wolnym. Kwas karboranowy został otrzymany i zbadany przez zespół z Uniwersytetu Kalifornijskiego w Riverside w 2004 r. (pl)
  • Ácidos carborano H(CXB11Y5Z6) (X, Y, Z = H, Alk, F, Cl, Br, CF3) são uma classe de superácidos. Estima-se que são um milhão de vezes mais fortes do que o ácido sulfúrico alguns 100% em termos das sua função de acidez de Hammet com valores (H 0 ≤ -18) e possuem os valores de pK a abaixo dos -20, estabelecendo-los como alguns dos mais fortes ácidos de Bronsted conhecidos. O exemplo mais bem estudado é o derivado altamente clorado H (CHB11Cl11 ). Verificou-se que a acidez do H(CHB11Cl11 ) excedia largamente a do ácido tríflico, CF3SO3H, e bistriflimide, (CF3SO2)2NH, compostos anteriormente considerados como os ácidos isolados mais fortes. (pt)
foaf:name
  • Carborane acids H[CXB11Y5Z6] (en)
name
  • Carborane acids H[CXB11Y5Z6] (en)
foaf:depiction
  • http://commons.wikimedia.org/wiki/Special:FilePath/Boron-Based_Carborane_Acid_Figure_3..jpg
  • http://commons.wikimedia.org/wiki/Special:FilePath/Boron-Based_Carborane_Acid_Figure_4..jpg
  • http://commons.wikimedia.org/wiki/Special:FilePath/Carborane-acid-3D-balls.png
  • http://commons.wikimedia.org/wiki/Special:FilePath/Carborane-acid.png
  • http://commons.wikimedia.org/wiki/Special:FilePath/Carborane_figure.png
  • http://commons.wikimedia.org/wiki/Special:FilePath/Generalcarboraneanion.png
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