Potassium tetrafluoronickelate is the inorganic compound with the formula K2NiF4. It features octahedral (high spin) Ni centers with Ni-F bond lengths of 2.006 Å. This green solid is a salt of tetrafluoronickelate. It is prepared by melting a mixture of nickel(II) fluoride, potassium fluoride, and potassium bifluoride. The compound adopts a perovskite-like structure consisting of layers of octahedral Ni centers interconnected by doubly bridging fluoride ligands. The layers are interconnected by potassium cations. It is one of the principal Ruddlesden-Popper phases. Early discoveries on cuprate superconductors focused on compounds with structures closely related to K2NiF4, e.g. lanthanum cuprate and derivative lanthanum barium copper oxide.
Property | Value |
---|---|
dbo:abstract |
|
dbo:thumbnail | |
dbo:wikiPageID |
|
dbo:wikiPageLength |
|
dbo:wikiPageRevisionID |
|
dbo:wikiPageWikiLink |
|
dbp:imagefile |
|
dbp:wikiPageUsesTemplate | |
dcterms:subject | |
rdf:type | |
rdfs:comment |
|
rdfs:label |
|
owl:sameAs | |
prov:wasDerivedFrom | |
foaf:depiction | |
foaf:isPrimaryTopicOf | |
is dbo:wikiPageRedirects of | |
is dbo:wikiPageWikiLink of | |
is foaf:primaryTopic of |