About: Phosphide silicide

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Phosphide silicides or silicide phosphides or silicophosphides are compounds containing anions composed of silicide (Si4−) and phosphide (P3−). They can be considered as mixed anion compounds. They are distinct from the phosphidosilicates, which have the phosphorus bonded to the silicon. Related compounds include the phosphide carbides, , , and . One preparation method is to heat a metal phosphide with silicon in a silica tube. Phosphorus must be prevented from evaporating. Another method is to use a liquid tin flux.

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  • Phosphide silicides or silicide phosphides or silicophosphides are compounds containing anions composed of silicide (Si4−) and phosphide (P3−). They can be considered as mixed anion compounds. They are distinct from the phosphidosilicates, which have the phosphorus bonded to the silicon. Related compounds include the phosphide carbides, , , and . One preparation method is to heat a metal phosphide with silicon in a silica tube. Phosphorus must be prevented from evaporating. Another method is to use a liquid tin flux. Phosphide silicides may be present as minerals. They are under investigation as photovoltaic materials. (en)
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  • Phosphide silicides or silicide phosphides or silicophosphides are compounds containing anions composed of silicide (Si4−) and phosphide (P3−). They can be considered as mixed anion compounds. They are distinct from the phosphidosilicates, which have the phosphorus bonded to the silicon. Related compounds include the phosphide carbides, , , and . One preparation method is to heat a metal phosphide with silicon in a silica tube. Phosphorus must be prevented from evaporating. Another method is to use a liquid tin flux. (en)
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  • Phosphide silicide (en)
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