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The Kornblum–DeLaMare rearrangement is a rearrangement reaction in organic chemistry in which a primary or secondary organic peroxide is converted to the corresponding ketone and alcohol under acid or base catalysis. The reaction is relevant as a tool in organic synthesis and is a key step in the biosynthesis of prostaglandins. The base can be a hydroxide such as potassium hydroxide or an amine such as triethylamine.

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  • The Kornblum–DeLaMare rearrangement is a rearrangement reaction in organic chemistry in which a primary or secondary organic peroxide is converted to the corresponding ketone and alcohol under acid or base catalysis. The reaction is relevant as a tool in organic synthesis and is a key step in the biosynthesis of prostaglandins. The base can be a hydroxide such as potassium hydroxide or an amine such as triethylamine. (en)
  • 科恩布卢姆-德拉马尔重排反应(Kornblum–DeLaMare rearrangement)指一级或二级有机过氧化物在下重排为相应的酮和醇。所用的碱可以为氢氧化钾或胺(如三乙胺)。 此反应在有机合成化学及前列腺素的生物合成中都有应用。 (zh)
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  • The Kornblum–DeLaMare rearrangement is a rearrangement reaction in organic chemistry in which a primary or secondary organic peroxide is converted to the corresponding ketone and alcohol under acid or base catalysis. The reaction is relevant as a tool in organic synthesis and is a key step in the biosynthesis of prostaglandins. The base can be a hydroxide such as potassium hydroxide or an amine such as triethylamine. (en)
  • 科恩布卢姆-德拉马尔重排反应(Kornblum–DeLaMare rearrangement)指一级或二级有机过氧化物在下重排为相应的酮和醇。所用的碱可以为氢氧化钾或胺(如三乙胺)。 此反应在有机合成化学及前列腺素的生物合成中都有应用。 (zh)
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  • Kornblum–DeLaMare rearrangement (en)
  • 科恩布卢姆-德拉马尔重排反应 (zh)
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