About: Tuck-in complex

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In organometallic chemistry, a tuck-in complex usually refers to derivatives of Cp* ligands wherein a methyl group is deprotonated and the resulting methylene attaches to the metal. The C5–CH2–M angle is acute. The term "tucked in" was coined to describe derivatives of organotungsten complexes. Although most "tucked-in" complexes are derived from Cp* ligands, other pi-bonded rings undergo similar reactions.

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  • In organometallic chemistry, a tuck-in complex usually refers to derivatives of Cp* ligands wherein a methyl group is deprotonated and the resulting methylene attaches to the metal. The C5–CH2–M angle is acute. The term "tucked in" was coined to describe derivatives of organotungsten complexes. Although most "tucked-in" complexes are derived from Cp* ligands, other pi-bonded rings undergo similar reactions. (en)
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  • In organometallic chemistry, a tuck-in complex usually refers to derivatives of Cp* ligands wherein a methyl group is deprotonated and the resulting methylene attaches to the metal. The C5–CH2–M angle is acute. The term "tucked in" was coined to describe derivatives of organotungsten complexes. Although most "tucked-in" complexes are derived from Cp* ligands, other pi-bonded rings undergo similar reactions. (en)
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  • Tuck-in complex (en)
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