Transition metal dithiophosphate complexes are coordination compounds containing dithiophosphate ligands, i.e. ligands of the formula (RO)2PS−2. The homoleptic complexes have formulas M[S2P(OR)2]2 and M[S2P(OR)2]3. These neutral complexes tend to be soluble in organic solvents, especially when R is branched. Perhaps the most important members are zinc dialkyldithiophosphates, which are oil additives. Such compounds are prepared by the reaction of dialkoxydithiophoric acid with metal oxides, chlorides, and acetates.
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