| dbo:abstract
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- Topochemical polymerization is a polymerization method performed by monomers aligned in the crystal state. In this process, the monomers are crystalized and polymerized under external stimuli such as heat, light, or pressure. Compared to traditional polymerization, the movement of monomers was confined by the crystal lattice in topochemical polymerization, giving rise to polymers with high crystallinity, tactility, and purity. Topochemical polymerization can also be used to synthesize unique polymers such as polydiacetylene that are otherwise hard to prepare. Various reactions have been adopted in the field of topochemical polymerization, such as [2+2], [4+2], [4+4], and [3+2] cycloaddition, linear addition between dienes, trienes, diacetylenes. Other than linear polymers, they can also be applied to the synthesis of two dimensional covalent networks. (en)
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| rdfs:comment
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- Topochemical polymerization is a polymerization method performed by monomers aligned in the crystal state. In this process, the monomers are crystalized and polymerized under external stimuli such as heat, light, or pressure. Compared to traditional polymerization, the movement of monomers was confined by the crystal lattice in topochemical polymerization, giving rise to polymers with high crystallinity, tactility, and purity. Topochemical polymerization can also be used to synthesize unique polymers such as polydiacetylene that are otherwise hard to prepare. (en)
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