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- Methyldiphenylphosphine is the organophosphine with the formula CH3(C6H5)2P, often abbreviated PMePh2. It is a colorless, viscous liquid. It is a member of series (CH3)3-n(C6H5)2P that also includes n = 0, n = 1, and n = 3 that are often employed as ligands in metal phosphine complexes. Methyldiphenylphosphine is prepared by reaction of chlorodiphenylphosphine with methyl Grignard reagent: Cl(C6H5)2P + CH3MgBr → CH3(C6H5)2P + MgBrCl Selected derivatives:
* The phosphine oxide OPMePh2, prepared by treatment with hydrogen peroxide.
* The coordination complex MoH4(PMePh2)4, prepared by treatment of MoCl4(PMePh2)2 with sodium borohydride in the presence of excess ligand.
* The coordination complex CoCl2(PMePh2)2, prepared by treating cobalt(II) chloride with the phosphine.
* The phosphine-borane H3BPMePh2 prepared by treating the phosphine with borane. (en)
- 甲基二苯基膦是一种有机化合物，化学式为C13H13P。它可由甲基溴化镁和二苯基氯化膦在乙醚中反应制得。甲基二苯基氧化膦被苯硅烷还原，也能得到甲基二苯基膦。它和硫或硒反应，可以得到相应的硫化膦或硒化膦。它和氯化镍反应，得到配合物二氯化二(甲基二苯基膦)合镍。 (zh)
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- 3681 (xsd:nonNegativeInteger)
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- Methyldiphenylphosphine.png (en)
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- 甲基二苯基膦是一种有机化合物，化学式为C13H13P。它可由甲基溴化镁和二苯基氯化膦在乙醚中反应制得。甲基二苯基氧化膦被苯硅烷还原，也能得到甲基二苯基膦。它和硫或硒反应，可以得到相应的硫化膦或硒化膦。它和氯化镍反应，得到配合物二氯化二(甲基二苯基膦)合镍。 (zh)
- Methyldiphenylphosphine is the organophosphine with the formula CH3(C6H5)2P, often abbreviated PMePh2. It is a colorless, viscous liquid. It is a member of series (CH3)3-n(C6H5)2P that also includes n = 0, n = 1, and n = 3 that are often employed as ligands in metal phosphine complexes. Methyldiphenylphosphine is prepared by reaction of chlorodiphenylphosphine with methyl Grignard reagent: Cl(C6H5)2P + CH3MgBr → CH3(C6H5)2P + MgBrCl Selected derivatives: (en)
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- Methyldiphenylphosphine (en)
- 甲基二苯基膦 (zh)
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