About: MIL-53

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MIL-53 (MIL ⇒ Matériaux de l′Institut Lavoisier) belongs to the class of metal-organic framework (MOF) materials. The first synthesis and the name was established by the group of Gérard Férey in 2002. The MIL-53 structure consists of inorganic [M-OH] chains, which are connected to four neighboring inorganic chains by therephthalate-based linker molecules. Each metal center is octahedrally coordinated by six oxygen atoms. Four of these oxygen atoms originate from four different carboxylate groups and the remaining two oxygen atoms belong to two different μ-OH moieties, which bridge neighboring metal centers. The resulting framework structure contains one-dimensional diamond-shaped pores. Many research group have investigated the flexibility of the MIL-53 structure. This flexible behavior, d

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  • MIL-53 (MIL ⇒ Matériaux de l′Institut Lavoisier) ist eine sehr bekannte und gut untersuchte Struktur der Materialklasse der Metall-organischen Gerüstverbindungen (MOFs). Sie wurde von der Arbeitsgruppe von Gérard Férey am Institut Lavoisier der Universität Versailles-Saint-Quentin-en-Yvelines hergestellt. Man unterscheidet MIL-53as (as = as synthesized, mit Einschlüssen von Terephthalsäure), MIL-53lt (lt = low temperature, die Tieftemperaturmodifikation) und MIL-53ht (ht = high temperature, die Hochtemperaturmodifikation). (de)
  • MIL-53 (MIL ⇒ Matériaux de l′Institut Lavoisier) belongs to the class of metal-organic framework (MOF) materials. The first synthesis and the name was established by the group of Gérard Férey in 2002. The MIL-53 structure consists of inorganic [M-OH] chains, which are connected to four neighboring inorganic chains by therephthalate-based linker molecules. Each metal center is octahedrally coordinated by six oxygen atoms. Four of these oxygen atoms originate from four different carboxylate groups and the remaining two oxygen atoms belong to two different μ-OH moieties, which bridge neighboring metal centers. The resulting framework structure contains one-dimensional diamond-shaped pores. Many research group have investigated the flexibility of the MIL-53 structure. This flexible behavior, during which the pore cross-section changes reversibly, was termed 'breathing.effect' and describes the ability of the MIL-53 framework to respond to external stimuli. (en)
  • MIL-53是一种金属有机框架材料，名称中字母缩写MIL为Matériaux de l′Institut Lavoisier，它由圣康丁昂伊夫利纳-凡尔赛大学拉瓦锡研究所的Gérard Férey组所合成。目前已知其它三价金属的类似物，如Al、Fe等。不同种类的MIL-53材料按下述区分：MIL-53as（as = as synthesized（合成原态），使用了对苯二甲酸）、MIL-53lt（lt = low temperature（低温），低温改性）和MIL-53ht（ht = high temperature（高温），高温改性）。 (zh)
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  • MIL-53 (MIL ⇒ Matériaux de l′Institut Lavoisier) ist eine sehr bekannte und gut untersuchte Struktur der Materialklasse der Metall-organischen Gerüstverbindungen (MOFs). Sie wurde von der Arbeitsgruppe von Gérard Férey am Institut Lavoisier der Universität Versailles-Saint-Quentin-en-Yvelines hergestellt. Man unterscheidet MIL-53as (as = as synthesized, mit Einschlüssen von Terephthalsäure), MIL-53lt (lt = low temperature, die Tieftemperaturmodifikation) und MIL-53ht (ht = high temperature, die Hochtemperaturmodifikation). (de)
  • MIL-53是一种金属有机框架材料，名称中字母缩写MIL为Matériaux de l′Institut Lavoisier，它由圣康丁昂伊夫利纳-凡尔赛大学拉瓦锡研究所的Gérard Férey组所合成。目前已知其它三价金属的类似物，如Al、Fe等。不同种类的MIL-53材料按下述区分：MIL-53as（as = as synthesized（合成原态），使用了对苯二甲酸）、MIL-53lt（lt = low temperature（低温），低温改性）和MIL-53ht（ht = high temperature（高温），高温改性）。 (zh)
  • MIL-53 (MIL ⇒ Matériaux de l′Institut Lavoisier) belongs to the class of metal-organic framework (MOF) materials. The first synthesis and the name was established by the group of Gérard Férey in 2002. The MIL-53 structure consists of inorganic [M-OH] chains, which are connected to four neighboring inorganic chains by therephthalate-based linker molecules. Each metal center is octahedrally coordinated by six oxygen atoms. Four of these oxygen atoms originate from four different carboxylate groups and the remaining two oxygen atoms belong to two different μ-OH moieties, which bridge neighboring metal centers. The resulting framework structure contains one-dimensional diamond-shaped pores. Many research group have investigated the flexibility of the MIL-53 structure. This flexible behavior, d (en)
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  • MIL-53 (de)
  • MIL-53 (en)
  • MIL-53 (zh)
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