About: Effective diffusion coefficient

The effective diffusion coefficient of a diffusant in atomic diffusion of solid polycrystalline materials like metal alloys is often represented as a weighted average of the grain boundary diffusion coefficient and the lattice diffusion coefficient. Diffusion along both the grain boundary and in the lattice may be modeled with an Arrhenius equation. The ratio of the grain boundary diffusion activation energy over the lattice diffusion activation energy is usually 0.4–0.6, so as temperature is lowered, the grain boundary diffusion component increases. Increasing temperature often allows for increased grain size, and the lattice diffusion component increases with increasing temperature, so often at 0.8 Tmelt (of an alloy), the grain boundary component can be neglected.