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- The du Noüy ring method is a technique for measuring the surface tension of a liquid. The method involves slowly lifting a ring, often made of platinum, from the surface of a liquid. The force, , required to raise the ring from the liquid's surface is measured and related to the liquid's surface tension, : where is the radius of the inner ring of the liquid film pulled and is the radius of the outer ring of the liquid film. is the weight of the ring minus the buoyant force due to the part of the ring below the liquid surface. When the ring's thickness is much smaller than its diameter, this equation can be simplified to: where R is the average of the inner and outer radius of the ring. This technique was proposed by the French physicist Pierre Lecomte du Noüy (1883–1947) in a paper published in 1925. The measurement is performed with a force tensiometer, which typically uses an electrobalance to measure the excess force caused by the liquid being pulled up and automatically calculates and displays the surface tension corresponding to the force. Earlier, torsion wire balances were commonly used. The maximum force is used for the calculations, and empirically determined correction factors are required to remove the effect caused by the finite diameter of the ring: with f being the correction factor. The most common correction factors include those by Zuidema and Waters (for liquids with low interfacial tension), Huh and Mason (which covers a wider range than Zuidema-Waters), and Harkins and Jordan (more precise than Huh-Mason while still covering the most widely used liquids). The surface tension and correction factors are expressed by the following equations: where is surface tension, R is the average diameter of the ring, and f is correction factor.
* Zuidema and Waters F = maximum pull of rings [dyn/cm] = density of the lower and upper phases a=0.7250 b =0.0009075 [s2.cm−1] r = Du Noüy wire radius R = Du Noüy ring radius
* Huh & Mason The correction factor is described as a function of and . See the references.
* Harkins and Jordan The correction factor is tabulated as a function of and . See the references. (en)
- Le tensiomètre à anneau de du Noüy est un appareil utilisant un anneau qui permet de mesurer la tension superficielle à une interface liquide-air et la tension interfaciale à une interface entre deux liquides non miscibles. Ce tensiomètre a été proposé par le physicien français Pierre Lecomte du Noüy (1883–1947) dans un article publié en 1925. Les normes NF EN 14210 et NF EN 14370 décrivent cette technique ainsi qu’une technique proche, celle de la plaque de Wilhelmy. (fr)
- デュヌイ法（デュヌイほう、英語: du Noüy ring method）とは、によって1925年に提案された、液体の表面張力を測定する方法の一つである。金属製の円環が測定対象の液面から離れるのに要した力を計測し、表面張力を算出する。リング法、輪環法、円環法とも。 (ja)
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- Le tensiomètre à anneau de du Noüy est un appareil utilisant un anneau qui permet de mesurer la tension superficielle à une interface liquide-air et la tension interfaciale à une interface entre deux liquides non miscibles. Ce tensiomètre a été proposé par le physicien français Pierre Lecomte du Noüy (1883–1947) dans un article publié en 1925. Les normes NF EN 14210 et NF EN 14370 décrivent cette technique ainsi qu’une technique proche, celle de la plaque de Wilhelmy. (fr)
- デュヌイ法（デュヌイほう、英語: du Noüy ring method）とは、によって1925年に提案された、液体の表面張力を測定する方法の一つである。金属製の円環が測定対象の液面から離れるのに要した力を計測し、表面張力を算出する。リング法、輪環法、円環法とも。 (ja)
- The du Noüy ring method is a technique for measuring the surface tension of a liquid. The method involves slowly lifting a ring, often made of platinum, from the surface of a liquid. The force, , required to raise the ring from the liquid's surface is measured and related to the liquid's surface tension, : where is the radius of the inner ring of the liquid film pulled and is the radius of the outer ring of the liquid film. is the weight of the ring minus the buoyant force due to the part of the ring below the liquid surface. where R is the average of the inner and outer radius of the ring. (en)
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- Du Noüy ring method (en)
- Tensiomètre à anneau de du Noüy (fr)
- デュヌイ法 (ja)
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