Diffusive–thermal instability or thermo–diffusive instability is an instrinsic flame instability that occurs both in premixed flames and in diffusion flames and arises because of the difference in the diffusion coefficient values for the fuel and heat transport, characterized by non-unity values of Lewis numbers. The instability mechanism that arises here is the same as in Turing instability explaining chemical morphogenesis, although the mechanism was first discovered in the context of combustion by Yakov Zeldovich in 1944 to explain the cellular structures appearing in lean hydrogen flames. Quantitative stability theory for premixed flames were developed by Gregory Sivashinsky (1977), Guy Joulin and Paul Clavin (1979) and for diffusion flames by Jong S. Kim (1997).
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