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Di-tert-butyl chromate is an alkoxide with the formula CrO2(OC(CH3)3)2. It is prepared by treatment of t-butanol with chromic anhydride. It forms red crystals at temperatures below –5 °C, above which it melts to give a red oil. The complex, which is diamagnetic, is of fundamental interest as a model for the intermediates in oxidations of alcohols by chromium(VI). This complex is stable because as a t-butyl groups lack beta-hydrogens. This complex and its analogues have tetrahedral geometry at chromium, as established by X-ray crystallography of its analogues.

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dbo:abstract
  • tert-Butylchromat ist eine chemische Verbindung aus der Gruppe der Ester, genauer Chromsäureester. Wie alle Chromsäurederivate ist sie krebserregend. Die Verbindung ist (außer in Lösung) instabil. (de)
  • Di-tert-butyl chromate is an alkoxide with the formula CrO2(OC(CH3)3)2. It is prepared by treatment of t-butanol with chromic anhydride. It forms red crystals at temperatures below –5 °C, above which it melts to give a red oil. The complex, which is diamagnetic, is of fundamental interest as a model for the intermediates in oxidations of alcohols by chromium(VI). This complex is stable because as a t-butyl groups lack beta-hydrogens. This complex and its analogues have tetrahedral geometry at chromium, as established by X-ray crystallography of its analogues. (en)
  • Alcocsaíd, leis an bhfoirmle [(CH3)3CO]2CrO2, is ea crómáit dé-treas-búitile. Ullmhaítear í trí t-bútánól a chóireáil le hainhidríd crómaí. Cruthaíonn sí criostail dhearga ag teochtaí faoi bhun –5 ° C, agus leáíonn sí chun ola dhearg a thabhairt. Tá spéis bhunúsach ag an gcoimpléasc, atá diamaighnéadach, mar mhúnla do na hidirmheánaigh in ocsaídiúcháin alcóil ag cróimiam (VI). Tá an coimpléasc seo seasmhach toisc mar t-ghrúpa bhúitile, níl béite-hidriginí aige. Tá geoiméadracht theitrihéidreach ag an coimpléasc seo agus a analógacha, mar a léirigh criostalagrafaíocht x-ghathach dá analógacha. (ga)
  • 铬酸叔丁酯是一种工业化学品,是一种有机的致癌物質。 (zh)
dbo:alternativeName
  • Di-tert-butyl ester of chromic acid; Bis(tert-butyl)chromate (en)
dbo:iupacName
  • tert-Butyl chromate (en)
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  • 48850114 (xsd:integer)
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  • 4217 (xsd:nonNegativeInteger)
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  • 1100329146 (xsd:integer)
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  • 2 (xsd:integer)
dbp:iupacname
  • tert-Butyl chromate (en)
dbp:name
  • tert-Butyl chromate (en)
dbp:othernames
  • Di-tert-butyl ester of chromic acid; Bischromate (en)
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rdfs:comment
  • tert-Butylchromat ist eine chemische Verbindung aus der Gruppe der Ester, genauer Chromsäureester. Wie alle Chromsäurederivate ist sie krebserregend. Die Verbindung ist (außer in Lösung) instabil. (de)
  • Di-tert-butyl chromate is an alkoxide with the formula CrO2(OC(CH3)3)2. It is prepared by treatment of t-butanol with chromic anhydride. It forms red crystals at temperatures below –5 °C, above which it melts to give a red oil. The complex, which is diamagnetic, is of fundamental interest as a model for the intermediates in oxidations of alcohols by chromium(VI). This complex is stable because as a t-butyl groups lack beta-hydrogens. This complex and its analogues have tetrahedral geometry at chromium, as established by X-ray crystallography of its analogues. (en)
  • Alcocsaíd, leis an bhfoirmle [(CH3)3CO]2CrO2, is ea crómáit dé-treas-búitile. Ullmhaítear í trí t-bútánól a chóireáil le hainhidríd crómaí. Cruthaíonn sí criostail dhearga ag teochtaí faoi bhun –5 ° C, agus leáíonn sí chun ola dhearg a thabhairt. Tá spéis bhunúsach ag an gcoimpléasc, atá diamaighnéadach, mar mhúnla do na hidirmheánaigh in ocsaídiúcháin alcóil ag cróimiam (VI). Tá an coimpléasc seo seasmhach toisc mar t-ghrúpa bhúitile, níl béite-hidriginí aige. Tá geoiméadracht theitrihéidreach ag an coimpléasc seo agus a analógacha, mar a léirigh criostalagrafaíocht x-ghathach dá analógacha. (ga)
  • 铬酸叔丁酯是一种工业化学品,是一种有机的致癌物質。 (zh)
rdfs:label
  • Tert-Butylchromat (de)
  • Di-tert-butyl chromate (en)
  • Crómáit dé-treas-búitile (ga)
  • 铬酸叔丁酯 (zh)
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  • tert-Butyl chromate (en)
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