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Chromium(III) boride, also known as chromium monoboride (CrB), is an inorganic compound with the chemical formula CrB. It is one of the six stable binary borides of chromium, which also include Cr2B, Cr5B3, Cr3B4, CrB2, and CrB4. Like many other transition metal borides, it is extremely hard (21-23 GPa), has high strength (690 MPa bending strength), conducts heat and electricity as well as many metallic alloys, and has a high melting point (~2100 °C). Unlike pure chromium, CrB is known to be a paramagnetic, with a magnetic susceptibility that is only weakly dependent on temperature. Due to these properties, among others, CrB has been considered as a candidate material for wear resistant coatings and high-temperature diffusion barriers.

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  • Chromium(III) boride, also known as chromium monoboride (CrB), is an inorganic compound with the chemical formula CrB. It is one of the six stable binary borides of chromium, which also include Cr2B, Cr5B3, Cr3B4, CrB2, and CrB4. Like many other transition metal borides, it is extremely hard (21-23 GPa), has high strength (690 MPa bending strength), conducts heat and electricity as well as many metallic alloys, and has a high melting point (~2100 °C). Unlike pure chromium, CrB is known to be a paramagnetic, with a magnetic susceptibility that is only weakly dependent on temperature. Due to these properties, among others, CrB has been considered as a candidate material for wear resistant coatings and high-temperature diffusion barriers. It can be synthesized as powders by many methods including direct reaction of the constituent elemental powders, self-propagating high-temperature synthesis (SHS), borothermic reduction, and molten salt growth. Slow-cooling of molten aluminum solutions from high-temperatures has been used to grow large single crystals, with a maximum size of 0.6 mm x 0.6 mm x 8.3 mm. CrB has an orthorhombic crystal structure (space group Cmcm) that was first discovered in 1951, and subsequently confirmed by later work using single crystals. The crystal structure can be visualized as slabs face-sharing BCr6 trigonal prisms, in the ac-plane, that are stacked parallel to the <010> crystallographic direction. Similar to Cr3B4 and Cr2B3, the B atoms in the structure form covalent bonds with each other and are characterized by unidirectional B-B- chains parallel to the <001> crystallographic direction. The transition metal monoborides VB, NbB, TaB, and NiB have the same crystal structure. (en)
  • Le borure de chrome(III) est un composé chimique de formule CrB. C'est l'un des six borures binaires stables du chrome, les autres étant Cr2B, Cr5B3, Cr3B4, CrB2 et CrB4. Il s'agit d'une céramique ultraréfractaire (point de fusion voisin de 2 100 °C), très dure (dureté Vickers de 21 à 23 GPa), très résistante (résistance à la flexion de 690 MPa), et présentant une conductivité électrique et thermique comparable à celle de nombreux alliages métalliques. À la différence du chrome pur, le borure de chrome(III) est paramagnétique, avec une susceptibilité magnétique qui ne dépend que faiblement de la température. Le borure de chrome(III) peut être obtenu sous forme de poudre par diverses méthodes telles que la réaction directe de poudres des corps simples le constituant, la synthèse auto-propagée à haute température (SHS), réduction borothermique et la croissance sous sel fondu. Le refroidissement lent de solutions d'aluminium fondu à des températures élevées a permis de faire croître de grands monocristaux pouvant atteindre 0,6 mm × 0,6 mm × 8,3 mm. Le borure de chrome(III) cristallise dans le système orthorhombique (groupe d'espace Cmcm) caractérisé une première fois en 1951 puis confirmé ultérieurement sur des monocristaux. On peut se représenter la structure cristalline de ce matériau comme constituée de plaques de prismes NCr6 trigonaux partageant une face commune dans le plan a–c et qui sont empilées parallèlement à la direction cristallographique <010>. Les atomes de bore établissent des liaisons covalentes entre eux en formant des chaînes B–B– unidirectionnelles parallèles à la direction <001>. Les monoborures de métaux de transition tels quceux de vanadium VB, de niobium NbB, de tantale TaB et de nickel NiB partagent la même structure. (fr)
  • Boreto de cromo(III) é um composto inorgânico de fórmula química CrB. (pt)
  • Монобори́д хро́ма — бинарное неорганическое соединение металла хрома и бора с формулой CrB, жёлтые кристаллы, не растворимые в воде. (ru)
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  • Chromium monoboride (en)
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  • boranylidynechromium (en)
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  • boranylidynechromium (en)
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  • Chromium monoboride (en)
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  • Boreto de cromo(III) é um composto inorgânico de fórmula química CrB. (pt)
  • Монобори́д хро́ма — бинарное неорганическое соединение металла хрома и бора с формулой CrB, жёлтые кристаллы, не растворимые в воде. (ru)
  • Chromium(III) boride, also known as chromium monoboride (CrB), is an inorganic compound with the chemical formula CrB. It is one of the six stable binary borides of chromium, which also include Cr2B, Cr5B3, Cr3B4, CrB2, and CrB4. Like many other transition metal borides, it is extremely hard (21-23 GPa), has high strength (690 MPa bending strength), conducts heat and electricity as well as many metallic alloys, and has a high melting point (~2100 °C). Unlike pure chromium, CrB is known to be a paramagnetic, with a magnetic susceptibility that is only weakly dependent on temperature. Due to these properties, among others, CrB has been considered as a candidate material for wear resistant coatings and high-temperature diffusion barriers. (en)
  • Le borure de chrome(III) est un composé chimique de formule CrB. C'est l'un des six borures binaires stables du chrome, les autres étant Cr2B, Cr5B3, Cr3B4, CrB2 et CrB4. Il s'agit d'une céramique ultraréfractaire (point de fusion voisin de 2 100 °C), très dure (dureté Vickers de 21 à 23 GPa), très résistante (résistance à la flexion de 690 MPa), et présentant une conductivité électrique et thermique comparable à celle de nombreux alliages métalliques. À la différence du chrome pur, le borure de chrome(III) est paramagnétique, avec une susceptibilité magnétique qui ne dépend que faiblement de la température. (fr)
rdfs:label
  • Chromium(III) boride (en)
  • Borure de chrome(III) (fr)
  • Boreto de cromo(III) (pt)
  • Борид хрома (ru)
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