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- Cerium(III) methanesulfonate is a white salt, usually found as the dihydrate with the formula Ce(CH3SO3)3·2H2O that precipitates from the neutralisation of cerium(III) carbonate with methanesulfonic acid, as first reported by L.B. Zinner in 1979. The crystals have a monoclinic polymeric structure were each methanesulfonate ion forms bonds with two cerium atoms, which present a coordination number of 8. The anhydrous salt is formed by water loss at 120 °C. Similar methanesulfonates can be prepared with other lanthanides. Cerium(III) methanesulfonate in solution is used as a precursor of electrogenerated cerium(IV), which is a strong oxidant and whose salts can be used in organic synthesis. The same principle of Ce(IV) electrogeneration is the fundamental reaction in the positive half-cell of the zinc–cerium battery. (en)
- 甲磺酸铈(III)是铈的甲磺酸盐，为白色固体，通常以二水合物Ce(CH3SO3)3·2H2O的形式由碳酸铈(III)和甲磺酸反应沉淀得到。它最初于1979年由L.B. Zinner制得。其晶体具有单斜聚合结构，每个甲磺酸根离子与两个8配位数的铈原子键合。无水盐可以通过水合物在120 °C的失水得到。其它镧系金属甲磺酸盐也能通过类似的方法制得。 甲磺酸铈(III)的溶液可以作为电化学法制备Ce(IV)的前体，Ce(IV)作为强氧化剂可用于有机合成。电化学法生成Ce(IV)是锌-铈电池阳极的基本半反应。 (zh)
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- 3761 (xsd:nonNegativeInteger)
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- Cerium methanesulfonate.svg (en)
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- 甲磺酸铈(III)是铈的甲磺酸盐，为白色固体，通常以二水合物Ce(CH3SO3)3·2H2O的形式由碳酸铈(III)和甲磺酸反应沉淀得到。它最初于1979年由L.B. Zinner制得。其晶体具有单斜聚合结构，每个甲磺酸根离子与两个8配位数的铈原子键合。无水盐可以通过水合物在120 °C的失水得到。其它镧系金属甲磺酸盐也能通过类似的方法制得。 甲磺酸铈(III)的溶液可以作为电化学法制备Ce(IV)的前体，Ce(IV)作为强氧化剂可用于有机合成。电化学法生成Ce(IV)是锌-铈电池阳极的基本半反应。 (zh)
- Cerium(III) methanesulfonate is a white salt, usually found as the dihydrate with the formula Ce(CH3SO3)3·2H2O that precipitates from the neutralisation of cerium(III) carbonate with methanesulfonic acid, as first reported by L.B. Zinner in 1979. The crystals have a monoclinic polymeric structure were each methanesulfonate ion forms bonds with two cerium atoms, which present a coordination number of 8. The anhydrous salt is formed by water loss at 120 °C. Similar methanesulfonates can be prepared with other lanthanides. Cerium(III) methanesulfonate in solution is used as a precursor of electrogenerated cerium(IV), which is a strong oxidant and whose salts can be used in organic synthesis. The same principle of Ce(IV) electrogeneration is the fundamental reaction in the positive half-cell o (en)
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- Cerium(III) methanesulfonate (en)
- 甲磺酸铈 (zh)
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_methanesulfonate.svg?width=300)
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