An Entity of Type: chemical substance, from Named Graph: http://dbpedia.org, within Data Space: dbpedia.org

2,2,4,4-Tetramethyl-3-t-butyl-pentane-3-ol or tri-tert-butylcarbinol is an organic compound with formula C13H28O, ((H3C)3C)3COH, or tBu3COH. It is an alcohol that can be viewed as a structural analog of a tridecane isomer where the central hydrogen has been replaced by a hydroxyl group -OH. Another structural analog, in which the COH group is replaced by N, is tri-tert-butylamine, a molecule predicted to be stable but has never been prepared.

Property Value
dbo:abstract
  • 2,2,4,4-Tetramethyl-3-t-butyl-pentane-3-ol or tri-tert-butylcarbinol is an organic compound with formula C13H28O, ((H3C)3C)3COH, or tBu3COH. It is an alcohol that can be viewed as a structural analog of a tridecane isomer where the central hydrogen has been replaced by a hydroxyl group -OH. Tri-tert-butylcarbinol is arguably the most sterically hindered alcohol that has been prepared to date. In contrast to all other known alcohols, the infrared spectrum of the liquid does not exhibit a broad OH absorption associated with intermolecular hydrogen bonding, making it interesting for research in spectroscopy. The bulky tert-butyl groups (H3C)3C- groups attached to the central carbon prevent the formation of a O–H---O hydrogen bond with another molecule, an intermolecular interaction typical of alcohols. Another structural analog, in which the COH group is replaced by N, is tri-tert-butylamine, a molecule predicted to be stable but has never been prepared. (en)
dbo:iupacName
  • 3-tert-Butyl-2,2,4,4-tetramethylpentan-3-ol (en)
dbo:thumbnail
dbo:wikiPageID
  • 25121528 (xsd:integer)
dbo:wikiPageLength
  • 3315 (xsd:nonNegativeInteger)
dbo:wikiPageRevisionID
  • 1105928547 (xsd:integer)
dbo:wikiPageWikiLink
dbp:imagefilel
  • 2244 (xsd:integer)
dbp:imagefiler
  • 2244 (xsd:integer)
dbp:name
  • 2244 (xsd:integer)
dbp:pin
  • 3 (xsd:integer)
dbp:verifiedfields
  • changed (en)
dbp:verifiedrevid
  • 477209644 (xsd:integer)
dbp:watchedfields
  • changed (en)
dbp:wikiPageUsesTemplate
dcterms:subject
gold:hypernym
rdf:type
rdfs:comment
  • 2,2,4,4-Tetramethyl-3-t-butyl-pentane-3-ol or tri-tert-butylcarbinol is an organic compound with formula C13H28O, ((H3C)3C)3COH, or tBu3COH. It is an alcohol that can be viewed as a structural analog of a tridecane isomer where the central hydrogen has been replaced by a hydroxyl group -OH. Another structural analog, in which the COH group is replaced by N, is tri-tert-butylamine, a molecule predicted to be stable but has never been prepared. (en)
rdfs:label
  • 2,2,4,4-Tetramethyl-3-t-butyl-pentane-3-ol (en)
owl:sameAs
prov:wasDerivedFrom
foaf:depiction
foaf:isPrimaryTopicOf
foaf:name
  • 2,2,4,4-Tetramethyl-3-t-butyl-pentane-3-ol (en)
is dbo:wikiPageRedirects of
is dbo:wikiPageWikiLink of
is foaf:primaryTopic of
Powered by OpenLink Virtuoso    This material is Open Knowledge     W3C Semantic Web Technology     This material is Open Knowledge    Valid XHTML + RDFa
This content was extracted from Wikipedia and is licensed under the Creative Commons Attribution-ShareAlike 3.0 Unported License