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Statements

Subject Item
dbr:Claus'_benzene
rdf:type
yago:Relation100031921 yago:Abstraction100002137 yago:AromaticHydrocarbon114767996 yago:Part113809207 yago:OrganicCompound114727670 yago:PhysicalEntity100001930 yago:WikicatAromaticHydrocarbons yago:Compound114818238 dbo:ChemicalSubstance yago:Hydrocarbon114911057 owl:Thing yago:Matter100020827 dbo:ChemicalCompound yago:Material114580897 n21:ChemicalObject yago:WikicatHydrocarbons yago:Chemical114806838 yago:Substance100019613 wikidata:Q11173
rdfs:label
Benzène de Claus 克劳斯苯 クラウスベンゼン Claus' benzene Benzene di Claus
rdfs:comment
クラウスベンゼン（英: Claus' benzene）は、化学式C6H6の仮説上の炭化水素であり、ベンゼンの異性体である。ベンゼンの構造がまだ論争中であった1867年にベンゼンのあり得そうな構造としてによって提唱された。この分子は炭素が六角形の角に位置し、それぞれの炭素が隣合う2つの炭素と反対側の向かい合う1つの炭素と結合した構造をしている。高いひずみエネルギーにより合成は不可能である。 克劳斯苯（英語：Claus' benzene）是描述苯的分子结构的一种假设，由德国化学家于1867年提出。这种结构又称对位键结构式，分子中每个碳原子与相邻两个碳原子以及对位的一个碳原子相连。但克劳斯苯的应变能极高，所以不可能合成。 La structure du benzène de Claus fut incorrectement proposée par Claus et Körner à la fin du XIXe siècle comme étant celle du benzène. Elle est constituée de six liaisons carbone-carbone réelles (le tour de l'hexagone) et de six liaisons « potentielles » (les diagonales de l'hexagone) qui assuraient la stabilité du benzène en se compensant mutuellement. Claus' benzene (C6H6) is a hypothetical hydrocarbon and an isomer of benzene. It was proposed by Adolf Karl Ludwig Claus in 1867 as a possible structure for benzene at a time when the structure of benzene was still being debated. The molecule can be described as a hexagon with carbon atoms positioned at the corners, with each carbon connected to its two ortho carbons (the nearest carbons) and the one para carbon connected diametrically. High strain energy makes its synthesis impossible. Although it is often referred to alongside Dewar benzene and prismane, it is not possible to synthesise it, while Dewar benzene and prismane can be. Il benzene di Claus è una molecola ipotetica proposta da Adolf Claus come struttura del benzene. Si tratta di un ciclo a sei termini in cui ogni atomo di carbonio è legato anche all'atomo posto sulla diagonale, questi darebbero stabilità alla molecola. A differenza di altre molecole che furono proposte come struttura del benzene e che poi si scoprì che avevano come corrispondente un altro composto chimico differente dal benzene (ad esempio il prismano), la struttura del benzene di Claus non corrisponde ad alcun composto chimico.
foaf:depiction
n16:Claus_benzene.svg
dcterms:subject
dbc:Hypothetical_chemical_compounds dbc:Isomerism
dbo:wikiPageID
26565644
dbo:wikiPageRevisionID
1098456055
dbo:wikiPageWikiLink
dbc:Isomerism dbr:Adolf_Karl_Ludwig_Claus dbr:Benzene dbr:Prismane dbr:Isomer dbr:Strain_energy dbr:Dewar_benzene dbr:Hydrocarbon n17:Claus_benzene.svg dbc:Hypothetical_chemical_compounds
owl:sameAs
dbpedia-ja:クラウスベンゼン dbpedia-zh:克劳斯苯 dbpedia-it:Benzene_di_Claus dbpedia-fr:Benzène_de_Claus n18:2XsRu freebase:m.0bh9c4_ wikidata:Q2709622 yago-res:Claus'_benzene
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dbo:thumbnail
n16:Claus_benzene.svg?width=300
dbp:imagefile
n17:Claus_benzene.svg
dbp:pin
Tetracyclo[2.2.0.02,5.03,6]hexane
dbo:abstract
克劳斯苯（英語：Claus' benzene）是描述苯的分子结构的一种假设，由德国化学家于1867年提出。这种结构又称对位键结构式，分子中每个碳原子与相邻两个碳原子以及对位的一个碳原子相连。但克劳斯苯的应变能极高，所以不可能合成。 クラウスベンゼン（英: Claus' benzene）は、化学式C6H6の仮説上の炭化水素であり、ベンゼンの異性体である。ベンゼンの構造がまだ論争中であった1867年にベンゼンのあり得そうな構造としてによって提唱された。この分子は炭素が六角形の角に位置し、それぞれの炭素が隣合う2つの炭素と反対側の向かい合う1つの炭素と結合した構造をしている。高いひずみエネルギーにより合成は不可能である。 Il benzene di Claus è una molecola ipotetica proposta da Adolf Claus come struttura del benzene. Si tratta di un ciclo a sei termini in cui ogni atomo di carbonio è legato anche all'atomo posto sulla diagonale, questi darebbero stabilità alla molecola. A differenza di altre molecole che furono proposte come struttura del benzene e che poi si scoprì che avevano come corrispondente un altro composto chimico differente dal benzene (ad esempio il prismano), la struttura del benzene di Claus non corrisponde ad alcun composto chimico. La structure du benzène de Claus fut incorrectement proposée par Claus et Körner à la fin du XIXe siècle comme étant celle du benzène. Elle est constituée de six liaisons carbone-carbone réelles (le tour de l'hexagone) et de six liaisons « potentielles » (les diagonales de l'hexagone) qui assuraient la stabilité du benzène en se compensant mutuellement. Claus' benzene (C6H6) is a hypothetical hydrocarbon and an isomer of benzene. It was proposed by Adolf Karl Ludwig Claus in 1867 as a possible structure for benzene at a time when the structure of benzene was still being debated. The molecule can be described as a hexagon with carbon atoms positioned at the corners, with each carbon connected to its two ortho carbons (the nearest carbons) and the one para carbon connected diametrically. High strain energy makes its synthesis impossible. Although it is often referred to alongside Dewar benzene and prismane, it is not possible to synthesise it, while Dewar benzene and prismane can be.
gold:hypernym
dbr:Hydrocarbon
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wikipedia-en:Claus'_benzene?oldid=1098456055&ns=0
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dbo:iupacName
Tetracyclo[2.2.0.02,5.03,6]hexane
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