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- In organometallic chemistry, a metal–ligand multiple bond describes the interaction of certain ligands with a metal with a bond order greater than one. Coordination complexes featuring multiply bonded ligands are of both scholarly and practical interest. Transition metal carbene complexes catalyze the olefin metathesis reaction. Metal oxo intermediates are pervasive in oxidation catalysis. As a cautionary note, the classification of a metal ligand bond as being "multiple" bond order is ambiguous and even arbitrary because bond order is a formalism. Furthermore, the usage of multiple bonding is not uniform. Symmetry arguments suggest that most ligands engage metals via multiple bonds. The term 'metal ligand multiple bond" is often reserved for ligands of the type CRn and NRn (n = 0, 1, 2) and ORn (n = 0, 1) where R is H or an organic substituent, or pseudohalide. Historically, CO and NO+ are not included in this classification, nor are halides. (en)
- En química, un enlace múltiple metal-ligando describe la interacción de ciertos ligandos con un metal, con un orden de enlace mayor que uno. Los complejos que muestran ligandos unidos por enlace múltiple son de interés académico y práctico. Los catalizan la reacción de . Los intermediarios oxo metal son pervasivos en la catálisis de oxidación. (es)
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- En química, un enlace múltiple metal-ligando describe la interacción de ciertos ligandos con un metal, con un orden de enlace mayor que uno. Los complejos que muestran ligandos unidos por enlace múltiple son de interés académico y práctico. Los catalizan la reacción de . Los intermediarios oxo metal son pervasivos en la catálisis de oxidación. (es)
- In organometallic chemistry, a metal–ligand multiple bond describes the interaction of certain ligands with a metal with a bond order greater than one. Coordination complexes featuring multiply bonded ligands are of both scholarly and practical interest. Transition metal carbene complexes catalyze the olefin metathesis reaction. Metal oxo intermediates are pervasive in oxidation catalysis. (en)
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- Násobná vazba kov–ligand (cs)
- Enlace múltiple metal ligando (es)
- Metal–ligand multiple bond (en)
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