About: Phenylsilver

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Phenylsilver is an organosilver compound with the chemical formula C6H5Ag. It is a white solid. The structure is assumed to be polymeric. Mesitylsilver is a tetramer.

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  • Phenylsilver is an organosilver compound with the chemical formula C6H5Ag. It is a white solid. The structure is assumed to be polymeric. Mesitylsilver is a tetramer. (en)
  • 苯基银是一种有机银化合物,化学式为C6H5Ag,为白色固体。它可由硝酸银的乙醇溶液在15 °C十分缓慢地滴加至过量的三烷基苯基锡(或−10 °C滴加至三烷基苯基铅)的乙醇溶液得到。如果使用硝酸银的饱和溶液,则会产生亮黄色的5C6H5Ag·2AgNO3。它也可由硝酸银和二苯基锌以1:2摩尔比在0 °C反应得到;若以1:1摩尔比反应,则会产生橙色的C6H5Ag·2AgNO3。早期使用苯基溴化镁合成的苯基银样品中因含镁盐或银盐的杂质,使其稳定性降低。 苯基银以5 °C/min升温时,67 °C分解;以10 °C/min升温时,47 °C爆炸。分解的反应方程式为: 2 C6H5Ag → C6H5-C6H5 + 2 Ag (zh)
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  • Silver phenyl.svg (en)
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  • Phenylsilver (en)
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  • Phenylsilver is an organosilver compound with the chemical formula C6H5Ag. It is a white solid. The structure is assumed to be polymeric. Mesitylsilver is a tetramer. (en)
  • 苯基银是一种有机银化合物,化学式为C6H5Ag,为白色固体。它可由硝酸银的乙醇溶液在15 °C十分缓慢地滴加至过量的三烷基苯基锡(或−10 °C滴加至三烷基苯基铅)的乙醇溶液得到。如果使用硝酸银的饱和溶液,则会产生亮黄色的5C6H5Ag·2AgNO3。它也可由硝酸银和二苯基锌以1:2摩尔比在0 °C反应得到;若以1:1摩尔比反应,则会产生橙色的C6H5Ag·2AgNO3。早期使用苯基溴化镁合成的苯基银样品中因含镁盐或银盐的杂质,使其稳定性降低。 苯基银以5 °C/min升温时,67 °C分解;以10 °C/min升温时,47 °C爆炸。分解的反应方程式为: 2 C6H5Ag → C6H5-C6H5 + 2 Ag (zh)
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  • Phenylsilver (en)
  • 苯基银 (zh)
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  • Phenylsilver (en)
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