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About: Vinylcyclopropane rearrangement     Goto   Sponge   Distinct   Permalink

An Entity of Type : yago:WikicatRearrangementReactions, within Data Space : dbpedia.org associated with source document(s)

Type: yago:WikicatCyclopropanesyago:Agent114778436yago:Anesthetic102710766yago:CausalAgent100007347yago:ChemicalProcess113446390yago:ChemicalReaction113447361yago:Cyclopropane103155661yago:Drug103247620yago:GeneralAnesthetic103433434yago:InhalationAnesthetic103570838yago:Matter100020827yago:NaturalProcess113518963yago:PhysicalEntity100001930yago:Process100029677diseaseyago:Substance100020090yago:WikicatRearrangementReactions New Facet based on Instances of this Class

The vinylcyclopropane rearrangement or vinylcyclopropane-cyclopentene rearrangement is a ring expansion reaction, converting a vinyl-substituted cyclopropane ring into a cyclopentene ring. Intense experimental as well as computational investigations have revealed that mechanistically, the vinylcyclopropane rearrangement can be thought of as either a diradical-mediated two-step and/or orbital-symmetry-controlled pericyclic process. The amount by which each of the two mechanisms is operative is highly dependent on the substrate.