About: Praseodymium(V) oxide nitride     Goto   Sponge   NotDistinct   Permalink

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Praseodymium(V) oxide nitride is a compound of praseodymium in the oxidation state of +5 with the formula PrNO, which was first reported in 2000, however, the compound wasn't verified to have an oxidation state of +5 until 2017. This compound is produced by the reaction of praseodymium metal and nitric oxide in 4K and solid neon. The crystal structure is linear with the praseodymium forming a triple bond with the nitrogen and a double bond with the oxygen. Calculation shows a significant level of f-orbital covalence of Pr-X bonds.

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  • Praseodymium(V) oxide nitride (en)
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  • Praseodymium(V) oxide nitride is a compound of praseodymium in the oxidation state of +5 with the formula PrNO, which was first reported in 2000, however, the compound wasn't verified to have an oxidation state of +5 until 2017. This compound is produced by the reaction of praseodymium metal and nitric oxide in 4K and solid neon. The crystal structure is linear with the praseodymium forming a triple bond with the nitrogen and a double bond with the oxygen. Calculation shows a significant level of f-orbital covalence of Pr-X bonds. (en)
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  • Praseodymium nitride oxide (en)
  • Praseodymium oxide nitride (en)
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  • Praseodymium(V) oxide nitride is a compound of praseodymium in the oxidation state of +5 with the formula PrNO, which was first reported in 2000, however, the compound wasn't verified to have an oxidation state of +5 until 2017. This compound is produced by the reaction of praseodymium metal and nitric oxide in 4K and solid neon. The crystal structure is linear with the praseodymium forming a triple bond with the nitrogen and a double bond with the oxygen. Calculation shows a significant level of f-orbital covalence of Pr-X bonds. (en)
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  • Praseodymium nitride oxide (en)
  • Praseodymium oxide nitride (en)
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