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About: Metallo-ene reaction     Goto   Sponge   NotDistinct   Permalink

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The metallo-ene reaction is a chemical reaction employed within organic synthesis. Mechanistically similar to the classic ene reaction, the metallo-ene reaction involves a six-member cyclic transition state that brings an allylic species and an alkene species together to undergo a rearrangement. The initial allylic group migrates to one terminus of the alkene reactant and a new carbon-carbon sigma bond is formed between the allylic species and the other terminus of the alkene reactant. In the metallo-ene reaction, a metal ion (Mg, Zn, Pd, Ni etc.) acts as the migrating group rather than a hydrogen atom as in the classic ene reaction.