The chalcogens react with each other to form interchalcogen compounds. Although no chalcogen is extremely electropositive, nor quite as electronegative as the halogen fluorine (the most electronegative element), there is a large difference in electronegativity between the top (oxygen = 3.44 — the second most electronegative element after fluorine) and bottom (polonium = 2.0) of the group. Combined with the fact that there is a significant trend towards increasing metallic behaviour while descending the group (oxygen is a gaseous nonmetal, while polonium is a silvery post-transition metal), this causes the interchalcogens to display many different kinds of bonding: covalent, ionic, metallic, and semimetallic.
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| - Interchalcogen (en)
- カルコゲン間化合物 (ja)
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| - The chalcogens react with each other to form interchalcogen compounds. Although no chalcogen is extremely electropositive, nor quite as electronegative as the halogen fluorine (the most electronegative element), there is a large difference in electronegativity between the top (oxygen = 3.44 — the second most electronegative element after fluorine) and bottom (polonium = 2.0) of the group. Combined with the fact that there is a significant trend towards increasing metallic behaviour while descending the group (oxygen is a gaseous nonmetal, while polonium is a silvery post-transition metal), this causes the interchalcogens to display many different kinds of bonding: covalent, ionic, metallic, and semimetallic. (en)
- カルコゲン間化合物(かるこげんかんかごうぶつ)とは、カルコゲン(第16族元素)が互いに反応したものである。 カルコゲンには、極度に電気陰性度がの元素も(最も陰性の高い元素である)フッ素ほど陰性の元素も含まれないが、カルコゲンの中で電気陰性度が最高のもの(酸素 = 3.44)と最低のもの(ポロニウム = 2.0)の間には大きな差がある。重いカルコゲンほど金属性が強くなる(酸素はガス状の非金属、一方ポロニウムは銀白色のポスト遷移金属)ことから、カルコゲン間化合物は共有結合、イオン結合、金属結合および半金属性と様々な結合をとる。 (ja)
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| - The chalcogens react with each other to form interchalcogen compounds. Although no chalcogen is extremely electropositive, nor quite as electronegative as the halogen fluorine (the most electronegative element), there is a large difference in electronegativity between the top (oxygen = 3.44 — the second most electronegative element after fluorine) and bottom (polonium = 2.0) of the group. Combined with the fact that there is a significant trend towards increasing metallic behaviour while descending the group (oxygen is a gaseous nonmetal, while polonium is a silvery post-transition metal), this causes the interchalcogens to display many different kinds of bonding: covalent, ionic, metallic, and semimetallic. (en)
- カルコゲン間化合物(かるこげんかんかごうぶつ)とは、カルコゲン(第16族元素)が互いに反応したものである。 カルコゲンには、極度に電気陰性度がの元素も(最も陰性の高い元素である)フッ素ほど陰性の元素も含まれないが、カルコゲンの中で電気陰性度が最高のもの(酸素 = 3.44)と最低のもの(ポロニウム = 2.0)の間には大きな差がある。重いカルコゲンほど金属性が強くなる(酸素はガス状の非金属、一方ポロニウムは銀白色のポスト遷移金属)ことから、カルコゲン間化合物は共有結合、イオン結合、金属結合および半金属性と様々な結合をとる。 (ja)
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