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Crystallization of polymers is a process associated with partial alignment of their molecular chains. These chains fold together and form ordered regions called lamellae, which compose larger spheroidal structures named spherulites. Polymers can crystallize upon cooling from melting, mechanical stretching or solvent evaporation. Crystallization affects optical, mechanical, thermal and chemical properties of the polymer. The degree of crystallinity is estimated by different analytical methods and it typically ranges between 10 and 80%, with crystallized polymers often called "semi-crystalline". The properties of semi-crystalline polymers are determined not only by the degree of crystallinity, but also by the size and orientation of the molecular chains.

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  • Kristallisation (Polymer) (de)
  • Crystallization of polymers (en)
  • Cristallisation d'un polymère (fr)
  • 高分子结晶 (zh)
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  • Crystallization of polymers is a process associated with partial alignment of their molecular chains. These chains fold together and form ordered regions called lamellae, which compose larger spheroidal structures named spherulites. Polymers can crystallize upon cooling from melting, mechanical stretching or solvent evaporation. Crystallization affects optical, mechanical, thermal and chemical properties of the polymer. The degree of crystallinity is estimated by different analytical methods and it typically ranges between 10 and 80%, with crystallized polymers often called "semi-crystalline". The properties of semi-crystalline polymers are determined not only by the degree of crystallinity, but also by the size and orientation of the molecular chains. (en)
  • 高分子结晶是高分子链部分排列起来的过程,在此过程中,高分子链折叠起来,形成有序的区域,这样的区域成为片晶,片晶可堆砌成更大的球形结构,称为。高分子可从熔体冷却结晶,也可通过机械拉伸或溶剂蒸發结晶。结晶影响高分子材料的光学、力学、热和化学性质。结晶度可通过多种分析方法测定,一般在10%到80%之间,因此,结晶高分子常被称之为半结晶高分子。结晶高分子的性质除了通过结晶度表征,还通过分子链的折叠大小和取向表征。 (zh)
  • Die Kristallisation von Polymeren ist bei einigen thermoplastischen Kunststoffen zu beobachten. Hier kommt es beim Erstarren der Schmelze zu einer partiellen Ordnung der Molekülketten im Polymer. Ausgehend von Kristallisationskeimen lagern sich die Molekülketten faltenförmig aneinander und bilden sogenannte Lamellen, welche durch amorphe Bereiche getrennt sind. Die Lamellen bilden Überstrukturen wie z. B. Sphärolithe. Neben dem Erstarren kann eine Kristallisation auch aus einer Lösung erfolgen. (de)
  • La cristallisation d'un polymère est une cristallisation observée dans certains polymères thermoplastiques. Lorsque la masse fondue d'un polymère se solidifie, il se produit un ordonnancement partiel des chaînes moléculaires dans ce polymère. À partir des noyaux de cristallisation, les chaînes moléculaires s’empilent sous forme de plis et forment ce que l'on appelle des lamelles. Ce sont les blocs de construction à partir desquelles d'autres unités structurelles telles que les sphérulites sont formées. En plus de la solidification, la cristallisation peut également avoir lieu à partir d'une solution ou par étirement. (fr)
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  • http://commons.wikimedia.org/wiki/Special:FilePath/Lamellenbildung_bei_der_Kristallisation_von_PolymerenEN.svg
  • http://commons.wikimedia.org/wiki/Special:FilePath/Spherulite2.png
  • http://commons.wikimedia.org/wiki/Special:FilePath/Atactic_polypropylene.svg
  • http://commons.wikimedia.org/wiki/Special:FilePath/Isotactic_polypropylene.svg
  • http://commons.wikimedia.org/wiki/Special:FilePath/Kristallisation_durch_Verstreckung_(Polymer)EN.svg
  • http://commons.wikimedia.org/wiki/Special:FilePath/Polymerketten_-_amorph_und_kristallinEN.svg
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