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Acetyl iodide is an organoiodine compound with the formula CH3COI. It is a colourless liquid. It is formally derived from acetic acid. Although far rarer in the laboratory than the related acetyl bromide and acetyl chloride, acetyl iodide is produced, transiently at least, on a far larger scale than any other acid halide. Specifically, it is generated by the carbonylation of methyl iodide in the Cativa and Monsanto processes, which are the main industrial processes that generate acetic acid. It is also an intermediate in the production of acetic anhydride from methyl acetate.

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  • Acetyl iodide (en)
  • Acetyliodid (de)
  • Iodure d'acétyle (fr)
  • Ioduro di acetile (it)
  • ヨウ化アセチル (ja)
  • Acetyljodide (nl)
  • Iodeto de acetila (pt)
  • 乙酰碘 (zh)
rdfs:comment
  • Acetyliodid ist eine chemische Verbindung aus der Gruppe der Carbonsäurehalogenide und organischen Iodverbindungen. (de)
  • L’iodure d'acétyle est un composé organique iodé de formule brute CH3COI. C'est un halogénure d'acyle dérivé de l'acide acétique CH3COOH dont il est un intermédiaire de synthèse dans le procédé Monsanto. (fr)
  • ヨウ化アセチル (Acetyl iodide) は、化学式 CH3COI で表される有機化合物であり、無色の液体である。形式的には酢酸から誘導される。実験室では、関連する臭化アセチルおよび塩化アセチルよりもはるかに珍しいが、少なくとも一時的には他のどの酸ハロゲン化物よりもはるかに大規模に生成される。具体的には、酢酸への主要な工業的製造法であるカティバ法およびモンサント法におけるヨウ化メチルのによって生成する。また、酢酸メチルから無水酢酸を製造する際の中間体でもある。 ヨウ化アセチルは、カルボン酸で処理すると、塩化アセチルなどのハロゲン化アシルに典型的な反応を示さない。代わりに、ヨウ化アセチルはほとんどのカルボン酸とヨウ化物/水酸化物交換を受ける。 CH3COI + RCO2H → CH3CO2H + RCOI (ja)
  • Lo ioduro di acetile è un alogenuro acilico di formula CH3C(O)I. Questo organoioduro è un liquido incolore fumante di odore pungente, formalmente derivato dell'acido acetico sostituendo l'ossidrile con un atomo di iodio. Nei laboratori è molto meno usato dei corrispondenti cloruro di acetile e bromuro di acetile, mentre a livello industriale è un importante intermedio nei processi Cativa e Monsanto per la produzione di acido acetico. Lo ioduro di acetile è un intermedio anche per la produzione di anidride acetica a partire dall'acetato di metile. (it)
  • Acetyljodide (IUPAC-naam: ethanoyljodide) is een organische verbinding met als brutoformule C2H3IO. Het is een kleurloze vloeistof met een scherpe geur, die hydrolyseert in water tot waterstofjodide. (nl)
  • Iodeto de acetila, C2H3IO, também conhecido como iodeto de etanoíla, é um iodeto ácido (também conhecido como iodeto de acila) derivado do ácido acético (ácido etanóico). (pt)
  • 乙酰碘(化学式:CH3C(O)I),又称碘乙酰、碘化乙酰。 (zh)
  • Acetyl iodide is an organoiodine compound with the formula CH3COI. It is a colourless liquid. It is formally derived from acetic acid. Although far rarer in the laboratory than the related acetyl bromide and acetyl chloride, acetyl iodide is produced, transiently at least, on a far larger scale than any other acid halide. Specifically, it is generated by the carbonylation of methyl iodide in the Cativa and Monsanto processes, which are the main industrial processes that generate acetic acid. It is also an intermediate in the production of acetic anhydride from methyl acetate. (en)
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  • http://commons.wikimedia.org/wiki/Special:FilePath/Acetyl-iodide-2D-skeletal.svg
  • http://commons.wikimedia.org/wiki/Special:FilePath/Acetyl-iodide-3D-vdW.png
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  • Acetyl-iodide-2D-skeletal.svg (en)
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  • Acetyl-iodide-3D-vdW.png (en)
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  • Skeletal formula of acetyl iodide (en)
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  • Spacefill model of acetyl iodide (en)
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  • Acetyl iodide (en)
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  • Ethanoyl iodide (en)
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has abstract
  • Acetyl iodide is an organoiodine compound with the formula CH3COI. It is a colourless liquid. It is formally derived from acetic acid. Although far rarer in the laboratory than the related acetyl bromide and acetyl chloride, acetyl iodide is produced, transiently at least, on a far larger scale than any other acid halide. Specifically, it is generated by the carbonylation of methyl iodide in the Cativa and Monsanto processes, which are the main industrial processes that generate acetic acid. It is also an intermediate in the production of acetic anhydride from methyl acetate. Upon treatment with carboxylic acids, acetyl iodide does not exhibit reactions typical of acyl halides, such as acetyl chloride. Instead, acetyl iodide undergoes iodide/hydroxide exchange with most carboxylic acids: CH3COI + RCO2H → CH3CO2H + RCOI (en)
  • Acetyliodid ist eine chemische Verbindung aus der Gruppe der Carbonsäurehalogenide und organischen Iodverbindungen. (de)
  • L’iodure d'acétyle est un composé organique iodé de formule brute CH3COI. C'est un halogénure d'acyle dérivé de l'acide acétique CH3COOH dont il est un intermédiaire de synthèse dans le procédé Monsanto. (fr)
  • ヨウ化アセチル (Acetyl iodide) は、化学式 CH3COI で表される有機化合物であり、無色の液体である。形式的には酢酸から誘導される。実験室では、関連する臭化アセチルおよび塩化アセチルよりもはるかに珍しいが、少なくとも一時的には他のどの酸ハロゲン化物よりもはるかに大規模に生成される。具体的には、酢酸への主要な工業的製造法であるカティバ法およびモンサント法におけるヨウ化メチルのによって生成する。また、酢酸メチルから無水酢酸を製造する際の中間体でもある。 ヨウ化アセチルは、カルボン酸で処理すると、塩化アセチルなどのハロゲン化アシルに典型的な反応を示さない。代わりに、ヨウ化アセチルはほとんどのカルボン酸とヨウ化物/水酸化物交換を受ける。 CH3COI + RCO2H → CH3CO2H + RCOI (ja)
  • Lo ioduro di acetile è un alogenuro acilico di formula CH3C(O)I. Questo organoioduro è un liquido incolore fumante di odore pungente, formalmente derivato dell'acido acetico sostituendo l'ossidrile con un atomo di iodio. Nei laboratori è molto meno usato dei corrispondenti cloruro di acetile e bromuro di acetile, mentre a livello industriale è un importante intermedio nei processi Cativa e Monsanto per la produzione di acido acetico. Lo ioduro di acetile è un intermedio anche per la produzione di anidride acetica a partire dall'acetato di metile. (it)
  • Acetyljodide (IUPAC-naam: ethanoyljodide) is een organische verbinding met als brutoformule C2H3IO. Het is een kleurloze vloeistof met een scherpe geur, die hydrolyseert in water tot waterstofjodide. (nl)
  • Iodeto de acetila, C2H3IO, também conhecido como iodeto de etanoíla, é um iodeto ácido (também conhecido como iodeto de acila) derivado do ácido acético (ácido etanóico). (pt)
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