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The interaction of an electromagnetic wave with an electron bound in an atom or molecule can be described by time-dependent perturbation theory. Magnetic dipole transitions describe the dominant effect of the coupling to the magnetic part of the electromagnetic wave. They can be divided into two groups by the frequency at which they are observed: optical magnetic dipole transitions can occur at frequencies in the infrared, optical or ultraviolet between sublevels of two different electronic levels, while magnetic Resonance transitions can occur at microwave or radio frequencies between angular momentum sublevels within a single electronic level. The latter are called Electron Paramagnetic Resonance (EPR) transitions if they are associated with the electronic angular momentum of the atom or

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  • Magnetic dipole transition (en)
  • 磁気双極子遷移 (ja)
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  • 磁気双極子遷移(じきそうきょくしせんい)は、電磁波の磁気的部分とのカップリングが支配的な効果を記述する。電磁波と、原子や分子中の束縛された電子との相互作用は時間依存した摂動論で記述できる。 観測されるときの振動数によって2つのグループに分けられる。 * 光学磁気双極子遷移は赤外光、可視光、紫外光によって、2つの異なる電子準位の副準位間で起こる。 * 磁気共鳴遷移はマイクロ波やラジオ波によって、1電子準位の中の角運動量の副準位間で起こる。 磁気共鳴遷移は、原子や分子中の電子の角運動量によるものである場合は電子スピン共鳴(EPR)と呼ばれ、原子核の角運動量によるものである場合は核磁気共鳴(NMR)と呼ばれる。 (ja)
  • The interaction of an electromagnetic wave with an electron bound in an atom or molecule can be described by time-dependent perturbation theory. Magnetic dipole transitions describe the dominant effect of the coupling to the magnetic part of the electromagnetic wave. They can be divided into two groups by the frequency at which they are observed: optical magnetic dipole transitions can occur at frequencies in the infrared, optical or ultraviolet between sublevels of two different electronic levels, while magnetic Resonance transitions can occur at microwave or radio frequencies between angular momentum sublevels within a single electronic level. The latter are called Electron Paramagnetic Resonance (EPR) transitions if they are associated with the electronic angular momentum of the atom or (en)
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  • The interaction of an electromagnetic wave with an electron bound in an atom or molecule can be described by time-dependent perturbation theory. Magnetic dipole transitions describe the dominant effect of the coupling to the magnetic part of the electromagnetic wave. They can be divided into two groups by the frequency at which they are observed: optical magnetic dipole transitions can occur at frequencies in the infrared, optical or ultraviolet between sublevels of two different electronic levels, while magnetic Resonance transitions can occur at microwave or radio frequencies between angular momentum sublevels within a single electronic level. The latter are called Electron Paramagnetic Resonance (EPR) transitions if they are associated with the electronic angular momentum of the atom or molecule and Nuclear Magnetic Resonance (NMR) transitions if they are associated with the nuclear angular momentum. (en)
  • 磁気双極子遷移(じきそうきょくしせんい)は、電磁波の磁気的部分とのカップリングが支配的な効果を記述する。電磁波と、原子や分子中の束縛された電子との相互作用は時間依存した摂動論で記述できる。 観測されるときの振動数によって2つのグループに分けられる。 * 光学磁気双極子遷移は赤外光、可視光、紫外光によって、2つの異なる電子準位の副準位間で起こる。 * 磁気共鳴遷移はマイクロ波やラジオ波によって、1電子準位の中の角運動量の副準位間で起こる。 磁気共鳴遷移は、原子や分子中の電子の角運動量によるものである場合は電子スピン共鳴(EPR)と呼ばれ、原子核の角運動量によるものである場合は核磁気共鳴(NMR)と呼ばれる。 (ja)
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