In chemistry, ligand close packing theory (LCP theory), sometimes called the ligand close packing model describes how ligand – ligand repulsions affect the geometry around a central atom. It has been developed by R. J. Gillespie and others from 1997 onwards and is said to sit alongside VSEPR which was originally developed by R. J. Gillespie and R Nyholm. The inter-ligand distances in a wide range of molecules have been determined. The example below shows a series of related molecules:
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