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About: Hiyama coupling     Goto   Sponge   NotDistinct   Permalink

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Type: yago:WikicatNameReactionsyago:WikicatSubstitutionReactionsyago:ChemicalProcess113446390yago:ChemicalReaction113447361yago:NaturalProcess113518963yago:PhysicalEntity100001930yago:Process100029677disease New Facet based on Instances of this Class

The Hiyama coupling is a palladium-catalyzed cross-coupling reaction of organosilanes with organic halides used in organic chemistry to form carbon–carbon bonds (C-C bonds). This reaction was discovered in 1988 by Tamejiro Hiyama and Yasuo Hatanaka as a method to form carbon-carbon bonds synthetically with chemo- and regioselectivity. The Hiyama coupling has been applied to the synthesis of various natural products. * : aryl, alkenyl or alkynyl * : aryl, alkenyl, alkynyl or alkyl * : Cl, F or alkyl * : Cl, Br, I or OTf