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About: Reversible-deactivation polymerization     Goto   Sponge   Distinct   Permalink

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Reversible-deactivation polymerization (RDP) is a form of polymerization propagated by chain carriers the some of which at any instant are held in a state of dormancy through an equilibrium process involving other species. An example of reversible deactivation anionic polymerization (RDAP) is group transfer polymerization of alkyl methacrylates, where the initiator and the dormant state is a silyl ketene acetal. Despite having some common features, RDP is distinct from living polymerization which requires a complete absence of termination and irreversible chain transfer.