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About: Residual topology     Goto   Sponge   NotDistinct   Permalink

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Residual topology is a descriptive stereochemical term to classify a number of intertwined and interlocked molecules, which cannot be disentangled in an experiment without breaking of covalent bonds, while the strict rules of mathematical topology allow such a disentanglement. Examples of such molecules are rotaxanes, catenanes with covalently linked rings (so-called ), and open knots (pseudoknots) which are abundant in proteins.