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Statements

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dbr:Insensitive_nuclei_enhanced_by_polarization_transfer
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INEPT Insensitive nuclei enhanced by polarization transfer
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Insensitive nuclei enhancement by polarization transfer (INEPT) is a signal enhancement method used in NMR spectroscopy. It involves the transfer of nuclear spin polarization from spins with large Boltzmann population differences to nuclear spins of interest with lower Boltzmann population differences. INEPT uses J-coupling for the polarization transfer in contrast to Nuclear Overhauser effect (NOE), which arises from dipolar cross-relaxation. This method of signal enhancement was introduced by Ray Freeman in 1979. Due to its usefulness in signal enhancement, pulse sequences used in heteronuclear NMR experiments often contain blocks of INEPT or INEPT-like sequences. 核磁気共鳴分光法におけるINEPT(Insensitive nuclei enhanced by polarization transfer) は、ボルツマン分布の差が大きいスピンから小さいスピンへ分極移動させることで、感度を向上させる手法である。核オーバーハウザー効果では分極移動にを用いているが、INEPTではJ結合を用いている。
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核磁気共鳴分光法におけるINEPT(Insensitive nuclei enhanced by polarization transfer) は、ボルツマン分布の差が大きいスピンから小さいスピンへ分極移動させることで、感度を向上させる手法である。核オーバーハウザー効果では分極移動にを用いているが、INEPTではJ結合を用いている。 Insensitive nuclei enhancement by polarization transfer (INEPT) is a signal enhancement method used in NMR spectroscopy. It involves the transfer of nuclear spin polarization from spins with large Boltzmann population differences to nuclear spins of interest with lower Boltzmann population differences. INEPT uses J-coupling for the polarization transfer in contrast to Nuclear Overhauser effect (NOE), which arises from dipolar cross-relaxation. This method of signal enhancement was introduced by Ray Freeman in 1979. Due to its usefulness in signal enhancement, pulse sequences used in heteronuclear NMR experiments often contain blocks of INEPT or INEPT-like sequences.
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