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Statements

Subject Item
dbr:Corey-Nicolaou_macrolactonization
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dbr:Corey–Nicolaou_macrolactonization
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dbr:Corey–Nicolaou_macrolactonization
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dbr:Elias_James_Corey
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dbr:Corey–Nicolaou_macrolactonization
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dbr:Corey–Nicolaou_macrolactonization
rdfs:label
科里-尼古劳大环内酯合成 Corey–Nicolaou macrolactonization Corey-Nicolaou-Makrolactonisierung
rdfs:comment
是羟基酸在温和条件下，非质子溶剂中分子内成环反应成环的反应。 由于的竞争，大环分子内羧酸和羟基形成内脂的反应一般需要在高度稀释的溶液中进行。1974年，科里和尼古勞报道了由催化的大環內酯合成法。温和的反应条件和非质子溶剂环境使该法被应用在很多全合成路线中。 Die Corey-Nicolaou-Makrolactonisierung (auch bekannt als Corey-Nicolaou-Doppelaktivierung) ist eine Namensreaktion der Organischen Chemie, die von Elias James Corey und Kyriacos Costa Nicolaou 1974 veröffentlicht wurde. Diese Synthese dient der Herstellung makrocyclischer Lactone (Makrolide). Corey–Nicolaou macrolactonization is a named reaction of organic chemistry, for the synthesis of lactones from hydroxy acids, found in 1974. The reaction should take place in a polar aprotic solvent with mild conditions, with the use of 2,2'-Dipyridyldisulfide and triphenylphosphine.
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Corey–Nicolaou macrolactonization
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K. C. Nicolaou dbr:Elias_James_Corey
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Name reaction
dbo:abstract
是羟基酸在温和条件下，非质子溶剂中分子内成环反应成环的反应。 由于的竞争，大环分子内羧酸和羟基形成内脂的反应一般需要在高度稀释的溶液中进行。1974年，科里和尼古勞报道了由催化的大環內酯合成法。温和的反应条件和非质子溶剂环境使该法被应用在很多全合成路线中。 Corey–Nicolaou macrolactonization is a named reaction of organic chemistry, for the synthesis of lactones from hydroxy acids, found in 1974. The reaction should take place in a polar aprotic solvent with mild conditions, with the use of 2,2'-Dipyridyldisulfide and triphenylphosphine. Die Corey-Nicolaou-Makrolactonisierung (auch bekannt als Corey-Nicolaou-Doppelaktivierung) ist eine Namensreaktion der Organischen Chemie, die von Elias James Corey und Kyriacos Costa Nicolaou 1974 veröffentlicht wurde. Diese Synthese dient der Herstellung makrocyclischer Lactone (Makrolide).
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dbr:K._C._Nicolaou
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