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Trithiapentalene is an organic bicyclic molecule containing two sulfur heterocycles. Its 10-π aromatic structure is similar to naphthalene. There has been a literature dispute about whether the connectivity among the three sulfur atoms is a case of rapid tautomerization between two valence tautomers or a 3-center 4-electron bond. The reactions have been little studied. It forms a dinickel complex upon reaction with bis(allyl)nickel.

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  • Trithiapentalene is an organic bicyclic molecule containing two sulfur heterocycles. Its 10-π aromatic structure is similar to naphthalene. There has been a literature dispute about whether the connectivity among the three sulfur atoms is a case of rapid tautomerization between two valence tautomers or a 3-center 4-electron bond. The reactions have been little studied. It forms a dinickel complex upon reaction with bis(allyl)nickel. (en)
dbo:alternativeName
  • 1,6,6aλ4-Trithiapentalene, 6a-Thiothiophthene, 6a-Thiathiophthene (en)
dbo:iupacName
  • 1λ4,2,8-Trithiabicyclo[3.3.0]octa-1(5),3,6-triene (en)
  • 7λ4-[1,2]Dithiolo[1,5-b][1,2]dithiole (en)
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  • File:Trithiapentalene-from-xtal-3D-bs-17.png (en)
  • File:Trithiapentalene.svg (en)
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  • Trithiapentalene is an organic bicyclic molecule containing two sulfur heterocycles. Its 10-π aromatic structure is similar to naphthalene. There has been a literature dispute about whether the connectivity among the three sulfur atoms is a case of rapid tautomerization between two valence tautomers or a 3-center 4-electron bond. The reactions have been little studied. It forms a dinickel complex upon reaction with bis(allyl)nickel. (en)
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  • Trithiapentalene (en)
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