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Triacetonamine is an organic compound with the formula OC(CH2CMe2)2NH (where Me = CH3). It is a colorless or white solid that melts near room temperature. The compound is an intermediate in the preparation of 2,2,6,6-tetramethylpiperidine, a sterically hindered base and precursor to the reagent called TEMPO. Triacetonamine is formed by the poly-aldol condensation of acetone in the presence of ammonia and calcium chloride: 3 (CH3)2CO + NH3 → OC(CH2CMe2)2NH + 2 H2O Reductive amination of triacetonamine gives 4-amino-2,2,6,6-tetramethylpiperidine.

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  • Triacetonamin ist eine chemische Verbindung und ein tetramethyliertes . (de)
  • Triacetonamine is an organic compound with the formula OC(CH2CMe2)2NH (where Me = CH3). It is a colorless or white solid that melts near room temperature. The compound is an intermediate in the preparation of 2,2,6,6-tetramethylpiperidine, a sterically hindered base and precursor to the reagent called TEMPO. Triacetonamine is formed by the poly-aldol condensation of acetone in the presence of ammonia and calcium chloride: 3 (CH3)2CO + NH3 → OC(CH2CMe2)2NH + 2 H2O Reductive amination of triacetonamine gives 4-amino-2,2,6,6-tetramethylpiperidine. It is primarily used as a stabilizer for plastics, typically via its conversion to number of hindered amine light stabilizers, but also finds use as a chemical feedstock. It is used to prepare the hindered amine 2,2,6,6-tetramethylpiperidine, CH2[CH2C(CH3)2]2NH, as well as the radical oxidizer 4-Hydroxy-TEMPO. (en)
  • トリアセトンアミン(triacetone amine)は、アセトンとアンモニアの縮合反応で得られる化合物である。 3 CH3C(O)CH3 + NH3 → OC(CH2C(CH3)2)2NH + 2 H2O 立体障害をもつアミン:2,2,6,6-テトラメチルピペリジンの合成に使われる。 (ja)
dbo:alternativeName
  • Triacetone amine (en)
dbo:iupacName
  • 2,2,6,6-Tetramethylpiperidin-4-one (en)
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  • Triacetonamine-Structural formula V1.svg (en)
dbp:name
  • Triacetone amine (en)
dbp:othernames
  • Triacetone amine (en)
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  • 2266 (xsd:integer)
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  • changed (en)
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  • 470612896 (xsd:integer)
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  • changed (en)
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  • Triacetonamin ist eine chemische Verbindung und ein tetramethyliertes . (de)
  • トリアセトンアミン(triacetone amine)は、アセトンとアンモニアの縮合反応で得られる化合物である。 3 CH3C(O)CH3 + NH3 → OC(CH2C(CH3)2)2NH + 2 H2O 立体障害をもつアミン:2,2,6,6-テトラメチルピペリジンの合成に使われる。 (ja)
  • Triacetonamine is an organic compound with the formula OC(CH2CMe2)2NH (where Me = CH3). It is a colorless or white solid that melts near room temperature. The compound is an intermediate in the preparation of 2,2,6,6-tetramethylpiperidine, a sterically hindered base and precursor to the reagent called TEMPO. Triacetonamine is formed by the poly-aldol condensation of acetone in the presence of ammonia and calcium chloride: 3 (CH3)2CO + NH3 → OC(CH2CMe2)2NH + 2 H2O Reductive amination of triacetonamine gives 4-amino-2,2,6,6-tetramethylpiperidine. (en)
rdfs:label
  • Triacetonamin (de)
  • トリアセトンアミン (ja)
  • Triacetonamine (en)
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  • Triacetone amine (en)
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