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- Sodium maleonitriledithiolate is the chemical compound described by the formula Na2S2C2(CN)2. The name refers to the cis compound, structurally related to maleonitrile ((CHCN)2). Maleonitriledithiolate is often abbreviated mnt. It is a "dithiolene", i.e. a chelating alkene-1,2-dithiolate. It is a prototypical non-innocent ligand in coordination chemistry. Several complexes are known, such as [Ni(mnt)2]2−. The salt is synthesized by treating carbon disulfide with sodium cyanide to give the cyanodithioformate salt, which eliminates elemental sulfur in aqueous solution: 2 NaCN + 2 CS2 → Na2S2C2(CN)2 + 1/4 S8 The compound was first described by Bähr and Schleitzer 1958. (en)
- 丁二腈二硫醇钠是一种硫醇盐,化学式为Na2S2C2(CN)2,其英文为Sodium maleonitriledithiolate,英语中的“maleonitrile”特指cis-化合物。其酸根可简写为mnt,它是一种的衍生物,如在配位化学中可作为过渡金属的。已知的配合物有数种,如[Ni(mnt)2]2−等。 丁二腈二硫醇钠可以通过二硫化碳和氰化钠在水溶液中反应,得到氰基双硫代甲酸盐(丁二腈二硫醇盐)并析出单质硫: 2 NaCN + 2 CS2 → Na2S2C2(CN)2 + 1/4 S8 该化合物最初于1958年被Bähr和Schleitzer报道。 (zh)
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- sodium mnt sodium maleonitriledithiolate (en)
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- Disodium (Z)-1,2-dicyanoethene-1,2-bis(thiolate) (en)
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- 3407 (xsd:nonNegativeInteger)
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- Sodium_maleonitriledithiolate.svg (en)
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- sodium mnt sodium maleonitriledithiolate (en)
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- Disodium -1,2-dicyanoethene-1,2-bis (en)
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- 丁二腈二硫醇钠是一种硫醇盐,化学式为Na2S2C2(CN)2,其英文为Sodium maleonitriledithiolate,英语中的“maleonitrile”特指cis-化合物。其酸根可简写为mnt,它是一种的衍生物,如在配位化学中可作为过渡金属的。已知的配合物有数种,如[Ni(mnt)2]2−等。 丁二腈二硫醇钠可以通过二硫化碳和氰化钠在水溶液中反应,得到氰基双硫代甲酸盐(丁二腈二硫醇盐)并析出单质硫: 2 NaCN + 2 CS2 → Na2S2C2(CN)2 + 1/4 S8 该化合物最初于1958年被Bähr和Schleitzer报道。 (zh)
- Sodium maleonitriledithiolate is the chemical compound described by the formula Na2S2C2(CN)2. The name refers to the cis compound, structurally related to maleonitrile ((CHCN)2). Maleonitriledithiolate is often abbreviated mnt. It is a "dithiolene", i.e. a chelating alkene-1,2-dithiolate. It is a prototypical non-innocent ligand in coordination chemistry. Several complexes are known, such as [Ni(mnt)2]2−. The salt is synthesized by treating carbon disulfide with sodium cyanide to give the cyanodithioformate salt, which eliminates elemental sulfur in aqueous solution: (en)
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- Sodium maleonitriledithiolate (en)
- 顺丁烯二腈二硫醇钠 (zh)
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