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- Polyorthoester sind gekennzeichnet durch die allgemeine Struktur –[–R–O–C(R1, OR2)–O–R3–]n–, wobei der Rest R2 auch Teil eines heterocyclischen Rings mit dem Rest R sein kann.Sie entstehen durch Umesterung von Orthoestern mit Diolen oder durch Polyaddition zwischen einem Diol und einem Diketenacetal, wie z. B. 3,9-Diethyliden-2,4,8,10-tetraoxaspiro[5.5]undecan. (de)
- Polyorthoesters are polymers with the general structure –[–R–O–C(R1, OR2)–O–R3–]n– whereas the residue R2 can also be part of a heterocyclic ring with the residue R. Polyorthoesters are formed by transesterification of orthoesters with diols or by polyaddition between a diol and a diketene acetal, such as 3,9-diethylidene-2,4,8,10-tetraoxaspiro[5.5]undecane. (en)
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- dbr:Propionic_acid
- dbr:United_States_Pharmacopeia
- dbr:1,2,6-Hexanetriol
- dbr:1,6-Hexanediol
- dbr:Gamma-Butyrolactone
- dbr:Glycolic_acid
- dbr:Physiological
- dbr:Transesterification
- dbr:3,9-Diethylidene-2,4,8,10-tetraoxaspiro(5.5)undecane
- dbr:Ethanol
- dbr:P-Toluenesulfonic_acid
- dbr:Diol
- dbr:Polymer_degradation
- dbc:Orthoesters
- dbr:Tetrahydrofuran
- dbr:Hydrolysis
- dbr:Hydrophobe
- dbc:Organic_polymers
- dbr:Lactic_acid
- dbr:Biodegradable_polymer
- dbr:Polymer
- dbr:Organism
- dbr:Catalysis
- dbr:Polyaddition
- dbr:Rate_equation
- dbr:Triol
- dbr:Octanedioic_acid
- dbr:Drug_implants
- dbr:PH_value
- dbr:2,2-diethoxytetrahydrofuran
- dbr:2-methylidenebutanedioic_acid
- dbr:Crosslinked_polymer
- dbr:Polycondensation
- dbr:4-hydroxybutanoic_acid
- dbr:5-fluorouracil
- dbr:Heterocyclic_ring
- dbr:Hexanedioic_acid
- dbr:1,4-Cyclohexanedimethanol
- dbr:Molecular_weights
- dbr:File:POE_I-Polyaddition.svg
- dbr:Crosslinking_density
- dbr:File:POE_I-Degradation.svg
- dbr:File:POE_II-Degradation.svg
- dbr:File:POE_II-Synthese.svg
- dbr:File:POE_III-Degradation.svg
- dbr:File:POE_III-Synthese_korr..svg
- dbr:File:POE_IV-Degradation.svg
- dbr:File:POE_IV-Synthese.svg
- dbr:Α,ω-diol
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rdfs:comment
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- Polyorthoester sind gekennzeichnet durch die allgemeine Struktur –[–R–O–C(R1, OR2)–O–R3–]n–, wobei der Rest R2 auch Teil eines heterocyclischen Rings mit dem Rest R sein kann.Sie entstehen durch Umesterung von Orthoestern mit Diolen oder durch Polyaddition zwischen einem Diol und einem Diketenacetal, wie z. B. 3,9-Diethyliden-2,4,8,10-tetraoxaspiro[5.5]undecan. (de)
- Polyorthoesters are polymers with the general structure –[–R–O–C(R1, OR2)–O–R3–]n– whereas the residue R2 can also be part of a heterocyclic ring with the residue R. Polyorthoesters are formed by transesterification of orthoesters with diols or by polyaddition between a diol and a diketene acetal, such as 3,9-diethylidene-2,4,8,10-tetraoxaspiro[5.5]undecane. (en)
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- Polyorthoester (de)
- Polyorthoester (en)
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- dbr:1,2,6-Hexanetriol
- dbr:Eirik_Solheim
- dbr:2,2-Diethoxytetrahydrofuran
- dbr:3,9-Diethylidene-2,4,8,10-tetraoxaspiro(5.5)undecane
- dbr:3,9-Divinyl-2,4,8,10-tetraoxaspiro(5.5)undecane
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