About: Metal–ligand multiple bond

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In organometallic chemistry, a metal–ligand multiple bond describes the interaction of certain ligands with a metal with a bond order greater than one. Coordination complexes featuring multiply bonded ligands are of both scholarly and practical interest. Transition metal carbene complexes catalyze the olefin metathesis reaction. Metal oxo intermediates are pervasive in oxidation catalysis.

Attributes	Values
rdfs:label	Násobná vazba kov–ligand (cs) Enlace múltiple metal ligando (es) Metal–ligand multiple bond (en)
rdfs:comment	En química, un enlace múltiple metal-ligando describe la interacción de ciertos ligandos con un metal, con un orden de enlace mayor que uno. Los complejos que muestran ligandos unidos por enlace múltiple son de interés académico y práctico. Los catalizan la reacción de . Los intermediarios oxo metal son pervasivos en la catálisis de oxidación. (es) In organometallic chemistry, a metal–ligand multiple bond describes the interaction of certain ligands with a metal with a bond order greater than one. Coordination complexes featuring multiply bonded ligands are of both scholarly and practical interest. Transition metal carbene complexes catalyze the olefin metathesis reaction. Metal oxo intermediates are pervasive in oxidation catalysis. (en)
foaf:depiction
dcterms:subject	Coordination chemistry Chemical bonding
Wikipage page ID	16285128 (xsd:integer)
Wikipage revision ID	1107698862 (xsd:integer)
Link from a Wikipage to another Wikipage	Carbon monoxide Coordination chemistry D electron count Double bond Coordination chemistry Orbital hybridisation Spectrochemical series Oxide Edward I. Solomon Coordination complex Chemical bonding Ligand Halide Oxo ligand Triple bond Angewandte Chemie Oxidation state Carbyne J. Am. Chem. Soc. Bond order Metal Olefin metathesis Organometallic chemistry Science (journal) Valence bond theory Imide Nitride Transition metal carbene complex Pseudohalide Brønsted acid Transition metal nitrido complex 18 electron rule Pi-acceptor ligand Oxo (ligand)
sameAs	Metal–ligand multiple bond Metal–ligand multiple bond Metal–ligand multiple bond Metal–ligand multiple bond Metal–ligand multiple bond
dbp:wikiPageUsesTemplate	dbt:Chem dbt:Citation_needed dbt:Reflist dbt:Short_description dbt:Organometallics dbt:Chemical_bonds
thumbnail	wiki-commons:Special:FilePath/MLMBond.png?width=300
has abstract	In organometallic chemistry, a metal–ligand multiple bond describes the interaction of certain ligands with a metal with a bond order greater than one. Coordination complexes featuring multiply bonded ligands are of both scholarly and practical interest. Transition metal carbene complexes catalyze the olefin metathesis reaction. Metal oxo intermediates are pervasive in oxidation catalysis. As a cautionary note, the classification of a metal ligand bond as being "multiple" bond order is ambiguous and even arbitrary because bond order is a formalism. Furthermore, the usage of multiple bonding is not uniform. Symmetry arguments suggest that most ligands engage metals via multiple bonds. The term 'metal ligand multiple bond" is often reserved for ligands of the type CRn and NRn (n = 0, 1, 2) and ORn (n = 0, 1) where R is H or an organic substituent, or pseudohalide. Historically, CO and NO+ are not included in this classification, nor are halides. (en) En química, un enlace múltiple metal-ligando describe la interacción de ciertos ligandos con un metal, con un orden de enlace mayor que uno. Los complejos que muestran ligandos unidos por enlace múltiple son de interés académico y práctico. Los catalizan la reacción de . Los intermediarios oxo metal son pervasivos en la catálisis de oxidación. (es)
prov:wasDerivedFrom	wikipedia-en:Metal–ligand_multiple_bond?oldid=1107698862&ns=0
page length (characters) of wiki page	7262 (xsd:nonNegativeInteger)
foaf:isPrimaryTopicOf	wikipedia-en:Metal–ligand_multiple_bond
is Link from a Wikipage to another Wikipage of	Actinocene Pi backbonding Metal-ligand multiple bond Metal ligand multiple bond Pi-donor ligands Π donation
is Wikipage redirect of	Metal-ligand multiple bond Metal ligand multiple bond Pi-donor ligands Π donation
is foaf:primaryTopic of	wikipedia-en:Metal–ligand_multiple_bond

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